Professional Documents
Culture Documents
Rakesh
Introduction
A Point defect
consists of a Silver
Ion that has moved
out of its normal
position in crystal
lattice (Interstitial
Ions).
Crystal Defects
A dislocation is a
line imperfection in
the crystal.
Cause a strain in
the wall structure.
Iodine ion strains
the crystal in this
way
Chemical sensitization
Chemical sensitization of the crystals
are produced by adding
allythiourea, a sulfur containing
compound to the emulsion , which
reacts with silver halide to form silver
sulfide.
Sensitization
Sensitivity
Speck
This Silver
Sulphide is
usually located
on surface of
the crystals and
is referred as
sensitivity
speck.
Sensitivity
speck by
Silver
sulfide
Point defect
in cubic
lattice.
Light photon
absorbed
by/ejectstrapped
Electron Br
electron
at sensitivity
speck
Neg electron
attracts interstitial
Ag+ ion
Ag+ and e -
combine to form
neutral
If >6-10(black)
Ag0 Ag
accumulate at
speck, it becomes
a latent image
center: ie, it is
Direct X-Ray Exposure of Film
Guards integrity
during processing
and fixing.
Super Coating
Thin layer of
Gelatin
Protects the
emulsion from
mechanical
damage
Prevents scratches
and pressure
marks.
Makes the film
smooth and slick
FILM PROCESSING
Film Processing
Series of events after the film is exposed to X-rays
EXPOSED GRAIN
Exposed silver bromide
grains possess a
weakness in the charge
barrier caused by the
presence of neutral silver
atoms, which have
collected at the sensitivity
speck.
This development center
enables electrons from the
developer to penetrate
the grain and reduce all its
silver ions to metallic
silver.
Development
Silver atoms at
latent image
center act as
catalyst
Grain either
develops
entirely or not
at all
Constituents Of The
Developer
Replenisher solution:
This consists of:
1. Solvent
2. Developing agents
3. Accelerator
4. Buffers
5. Restrainer
6. Preservative
7. Hardener
8. Sequestering agents
1. Solvent
Water is the solvent commonly used in replenisher
solution.
This also controls developer activity by diluting its effects.
It has a softening effect on the gelatin, thus allowing the
developing chemicals to penetrate the emulsion and act
on the silver halides.
The presence of calcium salts in the water (hard water)
may form a chalky deposit or scum on the surface of the
film.
More serious would be contamination of the solvent with
dissolved metals like copper and iron. The presence of
only a fewer parts per million of copper could cause
chemical fogging.
In practice, such effects are extremely rare.
2. Developing Agents
These are the reducing agents, which carry
out the primary function of supplying the
electrons that convert the exposed silver
halide grains to silver.
Characteristics:
1. Selectivity
2. High activity: Selectivity and activity tend to
be antagonistic properties.
An agent with high activity generally has low selectivity and
vice versa.
3. Should be resistant to bromide ions in the
solution.
No single agent satisfies all these
requirements Modern X-ray developers use a
combination of 2 developing agents phenidone
and hydroquinone known as PQ developer.
Phenidone is a quick acting reducing agent
capable of developing all exposed silver halide
grains. However, its selectivity is low and if
used alone would result in high fog levels.
Hydroquinone requires a strong alkaline
medium for its action. This is more selective
than phenidone but slower in onset of action.
Once its action has begun the development
proceeds vigorously although lightly exposed
grains are not affected by hydroquinone.
Alkaline
Medium
Advantages of PQ developers
1. Tolerant of increase in bromine ion
concentration.
2. High selectivity and low chemical fog.
3. Adequate activity even in low
concentrations.
4. Available in liquid concentrate form.
5. Fast acting
6. Adequate contrast
7. Super additive effect
SUPER ADDITIVE EFFECT
3. Accelerators: PQ developers need alkaline
medium for their action (10 - 11.5 pH).
Includes Sodium Hydroxide, Sodium
Carbonate and Borates.
This alkali is known as accelerator since its
effect is to accelerate the developing
process.
4. Buffers: It has the effect of maintaining
the pH of a solution within close limits.
Normally adequate buffering action is
provided by the carbonates used as
accelerators and sulphides used as
preservatives. Thus no additional buffers
are necessary.
5. Anti-
Foggants/Restrainers
Decrease the formation of Fog (fog is the
development of the unexposed silver halide grains
that do not contain a latent image ).
It also decrease the development of the latent
image.
Anti-foggants permit rapid development of exposed
grains at higher temp with minimized fog
development.
The development process itself produces as a
byproduct potassium bromide which is a very
effective restrainer.
So the developer replenisher need not include
potassium bromide among its constituents.
However it is usual to provide a powerful
restrainer / antifoggant such as benzotriazole.
6. Preservatives
Sodium sulphite
Oxidized products of developing agents form colored material that can
stain the emulsion, sodium sulphite forms colorless soluble products after
combining with colored oxidized products of developing agents
(sulfonates).
It acts as a preservative by preventing oxidation of hydroquinone by
removing dissolved oxygen in the solution and at the interface.
1. Constitution of developing
solution: For a particular level of
exposure image density depends both on
the emulsion characteristics and on the
developer activity. The developer activity
is influenced by
1. Choice of developing agents and their
relative proportions.
2. Concentration of developing agents in
solution.
3. pH of the developer solution.
4. Concentration of restrainer and
Factors affecting development:
1. Constitution of developing solution
2. Developer temperature
3. Development time
3. Development time:
Defined as the time between the entry of a specified part of
the film into the developing solution and exit from the
developing solution of the same part of the film.
1. Solvent
Water
2. Fixing Agent
2 agents:
Cyanides
Poisonous
Not generally used.
Thiosulfates - Sodium and Ammonium
Salt (more active) called Hypo.
7. Antisludging agent:
Boric acid is commonly used and this prevents
sludging of insoluble aluminium compounds in
the hardener.
Washing
Film must be washed well with water after
developing and fixing.
Removes all thiosulfite complexes.
Tap water is a satisfactory washing medium. In a
90 seconds cycle about 15 seconds is allowed for
the washing stage, while in manual processing a
minimum of 10 minutes is advised.
Incomplete wash causes retained hypo to react
with silver to form silver sulfide acquiring brown
colour.
Hypo + Silver
Silver Sulfide(brown) + Sodium sulfite
DRYING
All the surface water and most
of that retained in the
emulsion should be removed.
The drying medium is dry air
of low humidity, which
accelerates the evaporation
process and reduces drying
time.
Heated air can retain more
moisture than cold air and is
therefore a more effective
drying medium. However, the
excessive use of heat may
damage the film emulsion.
Air temperatures between 40-
650C are commonly used.
Total process of developing in schematic
The Automatic Film Processor
Processor (Top View)
4 Steps of Processing
Developing formation of the
image
Fixing stopping of
development, permanent fixing
of image on film
Deep
Racks Dryer
Turnaround
Water System
2 functions:
Washing the film
Temperature
control
Washing
Removes the last
traces of processing
chemicals and prevents
fading or discoloration.
This enables long term
storage capability
3. Temperature Control
System
Processing Temperatures
Maintains Developer 35 C
developer, fixer
Fixer 35 C
& dryer
temperature Wash 32-35 C
Dryer 57 C
4. Circulation or Recirculation
or Filtration System
Agitates developer solution
Removes reaction particles by the use of a
filtration system
Helps stabilize developer temperature.
Agitation and circulation
Agitation keeps solutions in contact with a
heater element in the bottom of the tank and
prevents layering of chemicals
Maintains developer temperature
Heating element is controlled by a thermostat
Recirculation System
Controlled by recirculation pumps that agitate solutions to
keep them mixed to maintain constant temperature
Circulation of water required to wash residual fixer (12 litres
per minute)
5. Replenishment
System
Fixer & developer levels drop as films
processed
System replaces lost chemicals
Microswitch of entrance rollers starts
replenishment pump stops when
film exits entrance rollers
Replenishment System
Typical replenishment rates: 60-70 mls of developer, and 100-
110 ml of fixer for every 14 inches of x-ray film (per 35 x
43cm crosswise film)
Types of Replenishment
Volume Replenishment
A volume of chemicals are replaced for
each film that is processed.
Flood Replenishment
Periodically replenishes chemicals
regardless of the number of films
processed.
6. Dryer System
Dries the film before its removal for
viewing
If not dry, difficult to hang on viewing
box
Consists of blower, ventilation ducts,
vented dryer tubes & exhaust system
Blower draws in air from room and
passes it over heating coils
Heated air enters ventilation ducts &
dryer tubes & then blows over film
Processing Rates
Processing Times
Amount of time it
takes a film to go Developer 20-25secs
through processor
Fixer 20
ranges from 45-210
seconds Wash 20
Film manufacturers
determine Dryer 25-30
temperatures and Travel 10
replenishment rates Time
Total Time 90 sec
Daylight Automatic
Processors
Enable film to be
processed without
need for darkroom
Special cassettes
Increase in department
efficiency, no need for
special darkroom staff
Disadvantages
Cost
Mechanical breakdowns
Automatic Film Processing:
Benefits
Compact size
Faster
Density and contrast is constant
Time and temperature controlled
Produces dry radiograph immediately
Automatic Film Processing:
Disadvantages
Artifacts caused by rollers.
Expensive and requires maintenance.
Manual processing required as a back
up in case of break down
Maintenance
To maintain quality, attention needed
in 3 areas:
1. Quality control
2. Processor cleanliness
3. Basic operation
DARK ROOM
CONSTRUCTION
LOCATION
Centrally located
Serviced by hatches
from the adjacent
imaging room
Away from damp or
hot areas
Accessible in terms of
power and water
supply
Adjoining viewing
room
SIZE
Minimum floor area of 10 sq meter
LABYRINTH
WHITE LIGHTING
SAFELIGHTING
WHITE LIGHTING
For inspection & maintenance of cassettes &
screens
Cleaning of work surfaces
Servicing of equipment
1.An increase in
gross fog;
2.An overall loss of
contrast.
DARK ROOM EQUIPMENTS
Automatic processor
Manual process unit
Processing chemicals
Hangers for suspending film
Cassette
Film storage hopper
Loading bench
Cupboards
AN AUTOMATIC PROCESSOR
MANUAL PROCESS UNIT
PROCESSING CHEMICALS
Hangers used for suspending films during processing
CASSETTES
FILM HOPPER FOR THE STORAGE OF UNEXPOSED FILMS
DARK ROOM DRY BENCH SYSTEM
Layout of a typical dark room : ample storage & work surfaces
HEALTH AND SAFETY IN THE
PROCESSING AREA
ELECTRICAL SAFETY
GENERAL SAFETY
CHEMICAL SAFETY
ELECTRICAL SAFETTY
All electrical equipments to be sited
well away from sinks & manual
processing units
Adequate earthing of all electrical
appliances
No trailing cables from appliances
Pull-cord switching for lights
GENERAL SAFETY
MEASURES
The maximum level of safe lighting
consistent with film sensitivity
Adequate ventilation
Second exits for fire safety
CHEMICAL HAZARDS
Processing chemicals contain many toxic
substances and must always be handled with care.
Staff should always be aware of the harmful
effects of exposure to the chemistry its fumes
through inhalation, ingestion or skin contact.
All staff involved with the handling of film
chemistry should be regularly advised to read
product labels and mixing instructions before
handling solutions.
Safety glasses, facemask, rubber gloves and
plastic apron should be available within the
processing area for each procedure.
Control of substances hazardous to
health (COSHH) Regulations 1988
Absorption Photographic
Variations Film Density
Variations
Tissue Absorption
Dependencies
Patient
composition
thickness Beam
energy spectrum
kVp
phase
filtration
Absorption Photographic
Variations Film Density
Variations
PHOTOGRAHIC OR OPTICAL
DENSITY
Measure of film blackness or opacity
PHOTOGRAHIC OR OPTICAL
DENSITY
Opacity is doubled by
an increase in density
of 0.3
Higher density
value means
darker film
less light transmitted
Base + Fog
Unexposed film has optical density > 0
(min = 0.12)
Base
The plastic material absorbs small amount of
light
blue dye
OD ~ 0.07
Fog
development of unexposed silver halide grains
OD ~ 0.05
Why Logarithms?
1. Easily represent Input Logarith
large dynamic m
100,000 5
ranges 10,000 4
factors of 10
1,000 3
2. Represent 100 2
physiologic 10 1
response of eye 1 0
to differences in
light intensity Using logarithms the
difference between
3. Densities can be
10,000 and 100,000 is
added the same as the
difference between 10
and 100
Why Logarithms?
1. Easily represent
large dynamic
ranges
factors of 10
2. Represent
physiologic
response of eye
to differences in O.D.=0.3
light intensity
+ O.D. = 0.8
3. Densities can be
O.D.=0.5
added
Plot derived by giving a film a series of exposures, developing the
film, and plotting the resulting density against the known exposure.
Sensitometric
Curve
Other Names:
Characteristic
Curve
H & D Curve (after
inventors Hurter &
Driffield)
Properties:
Base + fog
Dmax
Speed
Contrast
Latitude
Characteristic Curve
Linear portion in mid
densities
Flatter portions at
bottom & top
change in exposure
results in little density
change
Shoulder
flat portion of curve
near top
high exposure & density
Toe
flat portion of curve
near bottom
low exposure & density
Characteristic Curve
Straight Line
region
density
approximately
proportional to
log relative
exposure
Radiographic Contrast
Density
Density difference
Difference
Film
between image
Contrast areas
Depends upon
Subject contrast
Subject
Contrast Film contrast
Subject Contrast Dependency
Thickness
Density
Atomic differences
Energy spectrum
(kvp)
Contrast material
Scatter radiation
Film Contrast
Dependancy
1. Characteristic curve of the film
2. Film density
3. Screen or direct x-ray exposure
4. Film processing
1. Characteristic curve of
the film
Film Gamma
maximum slope of
characteristic curve
D2 - D1
Gamma = --------------------
log E2 - log E1
=1: no change in
subject contrast
<1: decreases
subject contrast
2. Contrast vs. Density
Subject contrast depends on density
Slope of H & D curve changes with
density
Optical
H & D Curve
Density
Slope of H & D
Definition of speed
reciprocal of exposure (in roentgens)
required to produce density of 1.0 above
base + fog
Optical
Density
1.0
B+F
log relative exposure
Speed & Contrast on the
curve
Contrast controls slope of
characteristic curve
Optical Lower
Density Contrast
Optical Higher
Density Contrast
Optical Slower
Density X Speed
Optical Faster
Density X Speed
Optical 2.0
Density
.25
log rel.
Latitude
exp.
Latitude
Inversely related to
contrast
high contrast = low
latitude
low contrast = high
latitude
Significance
Variation from optimal
technique less critical
higher range of subject
contrasts imaged on single
film (such as chest)
Double-Emulsion Film:
Advantages
Physical advantage
Emulsion shrinks when it dries
Having two emulsions minimizes curling
Photographic advantage
Faster system
Two screens used
DE film 2x contrast
Increase density Increase speed
Each emulsion optimally captures light
produced by its screen
double emulsion film screens
Double-Emulsion Film
Why use 2 thin emulsions rather than 1 thicker one?
Light photons are easily absorbed by the emulsion, however, only the
outer layer of the emulsion is affected by light from intensifying screens.
Light produced closer to emulsion
less light spread
X-Ray X-Ray
Crossover Exposure or
Print Through Exposure
Light from one screen exposes opposite
emulsion X-Ray
Top Top
Screen Emulsion
Film
Bottom Bottom
Screen Emulsion
Crossover X-Ray
caused by
incomplete
absorption of light
by adjacent
emulsion
poorer resolution
light travels further, spreads
more