Professional Documents
Culture Documents
1
Barrier Layers
Design considerations
Cost
Estimation of
permeability Slope stability
concerns
Selection of
landfill barrier
components Selection of barrier
Estimation of materials, slope,
leachate and thickness
generation
Long-term
durability
Main design consideration: minimize migration of leachate
from landfills and remove leachate efficiently
2
Barrier Materials
Clay: low permeability; availability; compaction
Existing soils: existence of fractures and root holes; amend
the existing soils with bentonite, fly ash, or cementing
materials
Geomembranes/flexible membrane liners (FMLs):
polyethylene and polyvinyl chloride; used on their own or as
part of a composite system Collection
drain
Refuse
Leachate
Filter fabric Drainage layer mound
(optional) Low permeability liner Clay liner
Native material
3
Single Composite Barrier Types
4
Double-Composite Barrier Types (1)
Waste
Waste 1.5 to 2 ft protective
2 ft protective soil layer soil layer
Geotextile filter
Geonet Geotextile
Geomembrane 1 ft sand or gravel
drainage layer
1.5 to 2 ft
compacted clay layer Geosynthetic
Primary Geotextile clay liner
composite Geonet 1 ft sand
liner drainage layer
Geomembrane
Geomembrane
3 ft compacted
Secondary 2 to 3 ft compacted
clay layer
composite clay layer
liner
5
Double-Composite Barrier Types (2)
Waste
2 ft soil layer
Waste Geotextile
2 ft sand 1 ft sand or gravel
4 in leachate collection leachate collection layer
pipe (placed directly (without and with
on geomembrane leachate collection pipes)
60 mil geomembrane 40 to 80 mil
2 ft compacted geomembran
clay layer e
1 ft sand leakage
6 in sand layer protection layer
1 ft compacted
40 to 80 mil
clay layer
geomembra
2 tone
4 ft compacted
clay layer
6
Materials Used in Natural Soil Liners
Types of Clay
Montmorillonite, kaolinite, and illite
Crystalline Structure of a Clay
Silicate tetrahedron (SiO4) and octahedron consisting of aluminum
(Al2(OH)6) or magnesium (Mg2(OH)6)
Clay groups CEC (meq/100 g) Specific surface (m2/g) Expansion index
Kaolinite 3~5 10 ~ 20
Sodium 0.20
Calcium 0.06
Illite 10 ~ 40 65 ~ 100
Sodium 0.15
Calcium 0.21
Montmorillonite 80 ~ 150 700 ~ 840
Sodium 2.5
Calcium 0.80
9
Soil Selection for Compacted Soil Liner (1)
Bentonite-soil admixture: Bentonite may be
added to clay-deficient soils in order to provide
a material with low hydraulic conductivity (< 1
10-7 cm/sec).
10
Placement Techniques (1)
Clay Liners
Properly select soil in terms of clay content
Use thicker liners to compensate for construction variability
Carefully supervise construction methods and quality control testing
Establish an effective monitoring program to reveal construction flaws
before serious problems occur
Use lysimeters in the field to monitor performance
Factors affecting compaction
Type of compaction, compactive effort, size of clods, bonding between
lifts, moisture contents
Optimum water content: saturation between 0.8 to 0.9; 0 to 3%
wet of optimum and at compactions equivalent to 95% Standard
Proctor (ASTM D698) or 90% modified American Society of
State Highway Transportation Organization (ASSHTO T99)
A wet-side compaction: low K because the soil particles are
arranged in a dispersed pattern
A dry-side compaction: a flocculated pattern, which offers better
paths for the flow of water and consequently high K
11
Sharp decrease in K
12
Placement Techniques (2)
Plastic clay: more difficult to break and compact in the field,
more sensitive, and less time to dry
Higher plasticity index: less permeable
Use clay with a plasticity index < 20 for ease of
installation and acceptable permeability
Desiccation: causes significant increase in K
Avoid by adding cover soil (> 0.3 to 1 m) or keeping
the soil moist by applying water during the periods in
which it is exposed;
A clay with a high liquid limit develops more
desiccation cracks ( 30 ~ 50%)
Freezing/thawing: causes irreversible increase in K; avoid
by adding cover soil or refuse in excess of the frost depth
Hydraulic conductivity measurements: in the lab vs. field;
exacerbated by the spatial variability of soil properties
and placement methods in the field.
Liquid limit measurement:
http://www.tecnotest.it/Products/Soil%20and%20Rock%20Mechanics/liquid_limit_description.htm 13
Laboratory Testing (1)
Ridged-wall permeameter
If the structure of the clay changes during permeation,
shrinkage, cracking, and/or piping can occur, this can result in
increased flow.
Flexible-wall permeameter
The confining pressure provided in a flexible-wall
permeameter can cause the clay to heal despite the structural
changes. As a result, little change in K is observed.
14
Laboratory Testing (2)
Use landfill leachate. If no leachate exists, use 0.01 N CaSO4-
added synthetic leachate.
If leachate-soil compatibility is not expected to be a problem, the
use of flexible wall permeameters with confining pressures
similar to those expected in the field is preferred.
Field-scale measurement
Measure seepage in the field using lysimeters; constructed in
and below the liner or in a trial liner
Double-ring infiltrometers may be employed during
construction.
Lysimeter
15
Construction Techniques
Construct the liner as a series of layers
Place individual layers in 15 cm (6 in.) lifts at 2 to 3% wet of
optimum moisture content to create a 0.7 to 1.3 m (2 to 4 ft)
overall thickness in a total of four to eight lifts
Compact each of the 15 cm lifts by a heavy-footed roller (30
tons) making several passes on each lift
Use the roller feet be sufficiently long to work the layer
being placed into the layer below to ensure good bonding
between the lifts of soil to minimize the formation of lateral
flow channels between the lifts. If lateral flow occurs,
significant increases in hydraulic conductivity will result.
In situ liner K >> one to two orders of magnitude greater than
lab measured K
Total liner thickness: sufficiently thick to avoid construction
irregularities (e.g., a min. of 0.75 m)
Commonly use composite liners with a geomembrane over a
barrier of natural material (i.e., compacted clay liner)
16
Compactor
17
Construction of Compacted Soil Liners
Soil compaction
Dumping clayey soil for (steel wheel compactor)
compaction
18
Contaminant Transport through Clay Liners
Diffusion is more dominant than advection.
Diffusion may transport contaminants at rates greater than
permeability-dependent advective flow.
Barriers may retard contaminants through the processes of
sorption, precipitation, biodegradation, and filtration.
Even though exposure of clay materials to landfill leachates
tends to increase permeability, permeability decreases because
of the biomass and precipitate accumulation at the clay
surface.
Carbonate Dissolution: likely to be modest
Cation Removal: by ion exchange, heavy metals are
attenuated (CEC value important)
Anion Removal: some are poorly attenuated
Other Inorganic Contaminants: no adverse effect on K
Attenuation of Biodegradable Organics: normally removed
19
Impact of Organic Solvents
Concentrated organic solvents could alter the structure of clay
soils and increase their Ks 100- to 1000-fold but not diluted
organic solvents.
Concentrated organic solvents cause shrinkage and cracking of
clay soils.
Volatile organic compounds (VOCs) tend to breakthrough quickly.
Organic liquid Group Representative liquids Comments on potential interaction
Organic acids Acetic acids Multiple potential attack mechanisms
Poor adsorption
Organic bases Aniline Rapid adsorption onto clays
Neutral polar Acetone, methanol Compete with H2O ethylene glycol
to wet clay
Reduce fluid viscosity
Adsorption inversely proportional to
solubility
Neutral nonpolar Xylene, heptane Dont compete with H2O to wet clay
Adsorb poorly onto clay
20
Field Performance
Compacted clay liners failed to exhibit field values of K of < 10-7
cm/sec due to inadequate design and installation procedures.
In Wisconsin, K < 10-7 cm/sec has been achieved through strict
design, installation, and quality assurance guidelines.
In metropolitan Toronto, K < 10-8 cm/sec was achieved.
Heavy metals were retained within the upper 15 cm of a clay liner,
with Fe, Zn, Cu, and Pb at background levels beyond the 15 cm
depth.
Diffusional transport of Cl- and Na+ reached 1.5 m into the clay in
15 years.
Leakage rates of 10 L/1000 m2/day, from full-scale landfills with
1.2 to 1.5 m thick clay liners have been reported.
Imcompatibility between MSW landfill leachate and the
compacted clay liners has not been a problem.
Liner K often decreased in the field because of sealing due to
precipitate formation, solids accumulation, and biomass growth
along the upper face of the liner and into cracks and fissures.
21
Landfill Environmental Monitoring Systems
Piezometer
installed as landfill
Single is being completed Landfill
composite or after landfill is
liner completed Ma
Double composite liner
22
Geosynthetics
In 1982, the U.S. EPA banned reliance on clay liners alone for
hazardous waste sites and stated that landfill should have a liner
that prevents migration of leachate during its active life.
The EPA came to the conclusion that a synthetic membrane leads
to virtually 100% removal efficiency and therefore specified use
of single or double liners using impermeable synthetic
membranes.
Synthetic membranes = impermeable ??? (permeable to organic
compounds)
No synthetic membrane is suitable for all wastes.
Geosynthetic includes:
Geonets: for drainage
Geogrids: for slope stability
Geomembranes: for isolation
Geotextiles: for reinforcement, separation, filtration, and
drainage
Geomats: for prevention of erosion of
exposed slopes such as landfill caps
23
Geonets
Used for lateral drainage by providing a
medium through which the planar flow of fluids can occur.
The geonet has minimal depth, but the grid like character
provides extensive flow opportunity.
K = 0.2 m/sec,
K = 0.003 m/sec,
Thickness = 4.5 10-3 m
Thickness = 0.3 m
T = 0.2 4.5 10-3 =
T = 0.003 0.3 Transmissivities?
0.0009 m2/sec
= 0.0009 m2/sec
Equivalent hydraulic
transmissivity
24
Geotextiles
Employed in the landfill as filters to
prevent the movement of soil fines into drainage
systems, to provide planar flow for drainage, or to act as
a cushion to protect geomembanes.
Typical K: 10-3 to 10-2 cm/sec comparable to sand
and gravels
Leachate drainage pipes should not be wrapped directly
in a geotextile because of potential clogging.
Should geotextiles be used on top of the drainage media
or as underlay or drainage underblanket?
Ref. Laboratory studies of clogging of landfill leachate
collection and drainage systems by Fleming and Rowe
Ensure that the initial lifts of waste being placed on top
of the leachate collection system have a low fines
content.
Sensitive to ultraviolet light
25
Geomembranes or
Flexible Membrane Liners (FMLs)
Very low-permeability membrane
liners used with any geotechnical
engineering materials so as to
minimize fluid flow across them.
Intended to limit the movement of leachate
Thicknesses: 0.75 mm (30 mil) to 3.00 mm (120 mil)
Due to failure of some smooth-surface
membranes along the shear plane,
textured geomembranes are used to
minimize slippage of the geomembrane
/soil interface.
26
Geomembrane Compositions
Polymers
Filters
Plasticizers
Carbon black
Additives
Scrim reinforcement
27
Geomembrane Types (1)
Thermoplastics
Soften upon heating and can be molded
e.g.: polyvinyl chloride (PVC), thermoplastic nitrile
(TN-PVC)
Crystalline thermoplastics
Polymeric chains folded in a crystal lattice, forming
lamellae (plate-like crystals)
Non-crystaline tie-molecules
connect lamellae:
More tie-molecules: flexibility
e.g.:
low-density polyethylene (LDPE), very low-
density polyethylene (VLDPE), high-density
polyethylene (HDPE), polypropylene, and elasticized
polyolefin
28
Geomembrane Types (2)
Thermoplastic elastomers
Can be molded
e.g.: chlorinated
polyethylene (CPE),
chlorosulfonated polyethylene (CSPE
or Hypalon), and thermoplastic ethylene-
propylene diene monomer (T-EPDM)
Elastomers
e.g.:
butyl rubber or isoprene isobutene
rubber, ethylene propylene diene monomer
(EPDM), neoprene, and polychloroprene
29
A Geomembrane-Lined Landfill for Special Hazardous
Waste (over 3 Million ft2 of Textured 80 mil HDPE)
30
Potential Problems with Geosynthetics
Ultraviolet degradation
UV radiation breaks polymer chains, make membrane brittle
Swelling
Exposure to liquids causes polymers to swell
Oxidative degradation (aging)
Oxygen reacts with polymers, makes membrane brittle rather
than flexible
Note: This takes 100s of years, accelerated by heat
Delamination
Separation of polymer layers
Extractive degradation
Extraction of particular component (such as plasticizer) from
polymer
Chemical degradation
Reaction of leachate components or organic chemicals with
liner 31
Additives
Fillers: used to reduce the cost and increase the stiffness without
altering the permeability - mineral particles, metallic oxides, fibers,
and reclaimed polymers (1~200 m)
Processing aids: used to reinforce or soften the compound during
the manufacturing process
Plasticizers: used to impart flexibility to the compounds, although
some plasticizers attract microorganism attack
Carbon black: used to impart a black color to the compound
which retards aging by ultraviolet light from the sun and increases
the stiffness of elastomeric compounds
Fungicides and biocides: used to prevent fungi and bacteria from
attacking the polymer
Antioxidants: used to reduce the aging effect of ultraviolet light
and ozone
Scrim reinforcement: used to increase the strength and improve
tear and puncture resistance; typically nylon or polyester
32
High Density Polyethylene (HDPE)
Semi-crystalline thermoplastic
Typical content
97% polyethylene
3% carbon black (for UV protection)
Traces (up to 1%) of stabilizers and antioxidant
Extruded
Properties
Most chemical resistant liner material
Low permeability
UV resistant (especially with carbon black and antioxidant)
30~140 mil-thick
Most widely used geomembrane
33
Linear Low-Density Polyethylene (LLDPE)
Semi-cystalline thermoplastic
Also called very flexible polyethylene (VFPE)
More flexible than HDPE used for non-uniform
surfaces such as lagoons, pond liners, and landfill caps
Extruded
Properties
Withstands tension, high elongation capability
Puncture and stress-crack resistant
Good chemical resistance
Low permeability
Good UV resistance
40~100 mil-thick
34
Coextruded HDPE and LLDPE
HDPE
LLDPE
HDPE
35
Coextruded HDPE and LLDPE
36
Flexible Polypropylene (fPP)
37
Polyvinyl Chloride (PVC)
One of the earliest geomembranes
Typical mix
35% resin, 30% plasticizer, 25% filler, 5~10% pigment,
2~3% additives
Properties
Good puncture resistance
Good chemical resistance (for non-polar compounds only)
Excellent flexibility
Easiest material to install, easier seam formation using
solvents
Low cost
38
Chlorosulfonated Polyethylene (CSPE or
Hypalon)
Thermoplastic elastomer: polymers cross-linked with sulfur
compounds
Always scrim reinforced (CSPE-R)
Also an early geomembrane
Used for exposed conditions like floating covers and
uncovered waste liners due to UV resistance
Thermoplastic initially: polymers crosslink over time and
become thermoset
Properties
Very good chemical resistance
(except aromatic hydrocarbons)
Excellent UV and temperature resistance
Fair to good tear, puncture resistance
Solvent or thermal seam
36 or 45 mil-thick
39
Butyl Rubber and Ethylene-Propylene
Rubber (EPDM)
Good resistance to UV and oxidation
Good temperature performance Butyl rubber
Low strength: butyl rubber
High strength: EPDM
Poor chemical resistance
Difficult to seam
Applications
Roofing
Impoundments
EPDM 40
Geomembranes or
Flexible Membrane Liners (FMLs)
HDPE: High density polyethylene
VLDPE: Very low density polyethylene
PVC: Polyvinyl chloride
CSPE-R: Chlorosulfonated polyethylene with fabric reinforcement
Properties of Geomembranes
Carbon
Resin Plasticizer Filler black or Additives Density Thickness
Type Width
% % % pigment % g/cm3 mil
%
HDPE 95~98 0 0 2~3 0.25~1 0.934~0.94 15 or 30 30~140
VLDPE 94~96 0 0 2~3 1~4 0.89~0.912 15 30~100
PVC 50~70 25~35 0~10 2~5 2~5 - 40~80 10~60
CSPE 40~60 0 40~50 5~40 5~15 min. 1.2 40~80 10~60
Market share:
HDPE & Very Flexible PE (VFPE) (60 mil): 60~65%
PVC (30 mil): 35~40%
41
Geomembrane Manufacturing
Extrusion
Molten polymer is extruded in a non-
reinforced sheet
Extrusion
Spreading
Coating of fabric with polymer
Calendering
Heated polymer passed
through series of rollers
Sometimes with two sheets
or with scrims
42
Geomembrane Testing Methods
Variety of physical and chemical tests to evaluate materials
ASTM methods for:
Tensile strength (ASTM D638)
Tear resistance (ASTM D1004)
Puncture resistance (ASTM D4833)
Low-temperature brittleness (ASTM D746)
Stress crack resistance (ASTM D1693)
Permeability
Carbon black content and diffusion (ASTM D1603 and D2663)
Accelerated heat aging (ASTM D573, D1349)
Density (ASTM D1505 or D792)
Melt flow index (ASTM D1238)
Thickness (ASTM D5199)
Ply adhesion (ASTM D413)
43
Geomembrane Stress-Strain
Source: U.S. EPA, 1994. Seminar
Publication: Design,
Operation, and Closure of
Municipal Solid Waste
Landfills. Report Number
EPA/625/R-94/008, Center
for Environmental Research
Information, U.S.
Environmental Protection
Agency, Cincinnati, Ohio.
September 1994.
(http://www.epa.gov/ORD/NRMR
L/Pubs/1994/625R94008.pdf )
44
Seaming
Critical factor for minimizing leakage
Required durability/polymeric properties: UV
stability, chemical stability, freeze-thaw stability,
biological stability, specific gravity, color, and water
sorption
Required mechanical properties: tensile modulus,
ultimate tensile strength, ultimate elongation, burst
strength, puncture strength, and creep strength
Methods
Thermal seaming
Chemical seaming
Extrusion or fusion welding
Mechanical methods
45
Thermal Seaming
Works with thermoplastic geomembranes only
(including crystalline thermoplastic)
Techniques
Hotwedge (or knife)
Used for long seams
Requires 4~6 inch overlap
Traveling vehicle moves along seam, heating top and
bottom membrane Air pocket
Step 3
The weld is finalized by
continuing application of heat
and sealing edge with roller.
48
Air Pressure Test
Requires that the channel between the two welds be
sealed at both ends and inflated to 30 psi (2 bar)
Test results are positive when the pressure does not
fall more than 5 psi (.33 bar) in 10 minutes.
The pressure in the channel stresses the weld
providing evidence of its integrity.
49
Extrusion or Fusion Welding
50
Alternative Field Seams for Geomembranes
51
Special Seaming Considerations
Fishmouths:
Wrinkles perpendicular to seam
Should be cut along wrinkle ridge, welded, and then
patched over
Cold weather and hot weather
Compromises seam quality
Rain or fog
Seams should be free of moisture and clean
52
Seam Testing
Trial welds
Welding of scrap pieces of geomembrane followed
by destructive testing of three 1-inch wide samples
Field tests
Seam tests
Vacuum tests
Destructive tests
53
Seam Strength Tests
Shear test
Peel test
54
Seam Tests
Used on double-track welds
Seal both ends with air injection needle welded in
Pressurize void between dual-track welds to 24 to 35
psi
Pressure should remain stable, indicating no leaks
Cut end opposite needle: void should depressurize,
demonstrating no blockage of channel
60
Advantages of GCLs
Easier and faster to construct, with lightweight
equipment
Simpler quality assurance (QA)
Comparable in cost to clay liner
Clay:$0.50 to $5.00 per ft2
GCL: $0.42 to $0.60 per ft2
Small thickness conserves landfill space
Better freeze-thaw, desiccation resistance
Withstand differential settlement better than clay
liners
61
Potential Failure Surfaces for a GCL
Potential failure surfaces
1. Interface between upper surface
of GCL and overlying material
2. Internal failure within GCL (can
be within bentonite or at the
internal interface between
bentonite and a geosysthetic
3. Interface between lower surface
of GCL and overlying material
62
Disadvantages of GCLs
65
Solvent Vapor Permeation
0.8 mm (30 mil) HDPE
66
Summary of Geomembrane Materials
Property HDPE CSPE PVC
Heat resistance
Microbial resistance ?
Chemical resistance
UV resistance
Puncture resistance ~ ~
Ease of placement
Cost Moderate High Low
Tensile strength ?
Cold weather problems -
Source: McBean, E. A., F. A. Rovers, and G. J. Farquhar, 1995. Solid Waste Landfill
Engineering and Design. Prentice Hall PTR, Upper Saddle River, New Jersey. 67
Geomembranes Leakage Rate
Darcys equation for geomembrane permeability
Q =K z Not valid when K is low (i.e.,
A T geomembrane K 10-12 cm/sec)
Poiseuilles equation for pinholes (during manufacturing)
gzd
Q = 128T
4
Q=0.976Cqo[1+0.1(h/tUM)0.95]d0.2h0.9kUM0.74 (1)
Cqo = dimensionless coefficient that characterizes the quality
of contact between the geomembrane and the
underlying medium (good = 0.21, poor = 1.15);
h = leachate head, m;
tUM = thickness of the low-permeability medium underlying
the geomembrane. m;
d = defect diameter, m; and
kUM = hydraulic conductivity of the low-permeability
medium underlying the geomembrane, m/sec.
71
Leakage Rate (Q, m3/sec) (2) [Giround et al.]
When a geomembrane is overlain and underlain by infinitely
permeable media (Bernoullis Equation),
Q=0.6a 2gh = 0.15d2 2gh (2)
a = defect area (m2).
When a geomembrane is underlain by an infinitely permeable
medium,
5 2 log d log k UM
n
Eq. 2
Eq. 3
Eq. 1
73
Leakage Rate
h ln 1 2
2
OMk 2 k
OM aq i 4g 0.6a overlying the geomembrane74
ak OM tan 2
A 2
;
qiL
q i k OM tan Q
B ;C
gL aq i
Q = kto2 (19)
Q
to t LCL (20)
k
k = hydraulic conductivity
of leachate collection
layer, L/T
to = max. thickness of
leachate in the leakage
collection layer
Leachate head
qiL
h
2k OM tan
76
Mass Flux through Geomembrane
80
5. A 2" prequalification strip of
membrane is taken from an extrusion
weld or a wedge weld seam and is
tested with a portable laboratory
tensiometer.
81
7. Wedge welder in the butt seam
placing slack wrinkle within the lining
system. Control of slack and potential
bridging of membrane are critical
factors for field installation.
87
Cap and Liner Profile
88