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Mechanism of dyeing with acid dyes
Acid dyes in aqueous solvent, produces a colored
anion, which can be described as follows.
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When describing the detail in above equation in
Protein fibers contain amino and carboxyl
groups, ionized mostly to NH3+ and COO-
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The action of Retarding agents in Acidic
Dye bath
Electrolyte (Nacl) in the acid dye bath acts as
a retarding agent because of chlorides ions
attracted by the positive sites at the fiber and
in the competition between.
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Acid dyes are divided into three groups
based on their differences in
Affinity
Based on the leveling properties
Economy of the dyeing and fastness
properties
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Leveling dyes
Highest level dyeing properties.
Quite combinable in trichromatic
shades.
Relatively small molecule therefore high
migration before fixation.
Low wet fastness therefore normally not
suited for apparel fabric.
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Milling dyes
Medium to high wet fastness.
Some milling dyes have poor light fastness in
pale shades.
Generally not combinable. Used as self shades
only.
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Metal complex acid dyes
More recent chemistry combined transition
metals with dye precursors to produce metal
complex acid dyes with the highest light
fastness and wet fastness. These dyes are
Economical.
Very good light fastness even in pale
shades
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Acid Dye
Structures
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Dye Structures
Acid dyes usually have a sulfo or carboxy group
on the molecule making them soluble in water.
Most acid dyes are related in basic structure to
the following:
Anthraquinone
Many acid dyes are synthesized from chemical
intermediates which form anthraquinone-like
structures as their final state. Many blue dyes
have this structure as their basic shape.
The structure predominates in the levelling class
of acid dye.
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Synthetic dyes are often derived from 9,10-
anthraquinone, such as alizarin. Important
derivatives are 1-nitroanthraquinone,
anthraquinone-1-sulfonic acid, and the
dinitroanthraquinone.
Bromocresol green
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Acid Dyeing
Techniques
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Acid dyeing techniques
Textile Auxiliaries used in acid dyeing
Leveling agent - for levelness dyeing
Retarding agent - for inhibiting the dye not
attach to fibers too fast
Acid - adjust the dyeing condition and
make the fibers to show positive charges
Water - dyeing media
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Dyeing temperature
The dyeing is generally carried out at boiling
temperature for 30- 60 minutes depending
upon the depth of the shade and dyestuffs
used.
Dyeing leveling agents
In the case dyeing with acid dyes , mainly
cationic agents such as ethoxylated fatty
amines are used as leveling agents.
Heating rates
Heating rate is generally kept 1-30C/Min
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Wool dyeing method with acid
dyes
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Detail about the graph
At A set bath at 50 with: 2% Formic
Acid (85%) 5% Glaubers Salt
anhydrous
pH 3.5 to 4.5
At B add required amount of dye.
At C add 2% Sulphuric Acid (96%) or
2% Formic Acid (85%).
Thoroughly rinse after dyeing to
remove loose colour.
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A dyeing cycle for Nylon filament dyeing
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Group Members with their
Contributions
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