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uk A2 1029 01-Jun-2016
INTRODUCTION
Strength of adsorption:
Nature of catalyst
Poisoning
Some substances may block active sites (i.e. they adsorb and
will not come off). Can ruin catalyst.
e.g. S in Haber process
e.g. Pb in catalytic converters
V2O4 + O2 V2O5
1) X + H+ HX+
2) HX+ + Y products + H+
No H+ catalyst
SLOW step
:
H+
With H+ catalyst : +
FASTER - H+
Fe2+ or Fe3+
e.g. 2 I- + S2O82- I2 + 2 SO42-
0 +
+ 0.54 V + 1.51 V
I2 + 2 e- 2 I- S2O82- + 2 e- 2 SO42-
+ 0.77 V
Fe3+ + e- Fe2+
Mn2+
e.g. 2 MnO4- + 16 H+ + 5 C2O42- 2 Mn2+ + 8 H2O + 10 CO2