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Concentration, C Cu [at.%]
slope, (dNCu/dx),
60
at CCu=71 at.%
40
20
0
0 0.05 0.1 0.15 0.2
Distance, x [cm]
Exercise
To determine the interdiffusion coefficient perform a Boltzmann–Matano analysis.
2
X
t
k(
const.)
)
t
The corresponding marker speed is
u
X
t k
M
t 2
Xt
uM
Xt
2t
Exercise
Calculate um
Xt 200[m]
uM
2t 2 (300) (3600) s
9.3 10 5 [m / s].
Velocity of lattice drifting v = marker velocity Um
Insert the marker speed uM , D, and the local concentration gradient, dNCu /dx
uM 9.3109[cm/s] DCu DNi 13.8[mol.frac./cm],
~ 1 C dx 1 C dx 1 C dx
D xdC xdC / C0 xdX
2t C0 dC 2t C0 dC / C0 2t C0 dX
1
(0.0106mol. frac cm) 0.072cm / mol. frac. 3.161010[cm2 /s]
2 300 3600s
~
D X A DB X B DA 0.71 DNi 0.29DCu 3.161010[cm2 /s]
9.310 [cm/s] DCu DNi 13.8[mol.frac./cm] (1)
9