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Equations:
Mg(s) + H2O(g) MgO(s) + H2(g)
Zn(s) + H2O(g) ZnO(s) + H2(g)
3Fe(s) + 4H2O(g) Fe3O4(s) + 4H2(g)
Chapter 19
Metals and Their Reactivity
Reaction of magnesium with steam
An experiment is set up as
shown in the diagram.
When the test tube is heated,
steam is produced which reacts
with the hot magnesium ribbon.
The magnesium reacts with the steam,
producing hydrogen gas which burns at the
jet of the glass tube.
Mg + H2O MgO + H2
Chapter 19
Metals and Their Reactivity
Reactions with dilute acids Potassium (K)
Sodium (Na)
All metals from lead and above
Calcium (Ca)
react with dilute acids to form a
……………………
salt and hydrogen.
Magnesium (Mg)
React with
The higher the metal is in the Aluminium (Al)
dilute acids
reactivity series, the more Zinc ( Zn)
vigorous the reaction. Iron (Fe)
Lead (Pb)
Potassium, sodium and
……………………
calcium will explode with
No reaction Copper (Cu)
acids, while lead will only react with dilute Silver (Ag)
very slowly when heated. acids
Chapter 19
Metals and Their Reactivity
Reactions of metals with dilute hydrochloric acid
Reduced by Copper
hydrogen Silver
Chapter 19
Metals and Their Reactivity
Reduction of metal oxides by carbon
Oxides of metals which are below carbon in the
reactivity series are reduced to the metal when
heated with carbon.
This process is used in the industry to obtain the
metals from their ores.
Examples:
Zn + CuSO4 ZnSO4 + Cu
Copper
The zinc has displaced the copper from the coating
copper(II) sulphate solution because zinc is
more reactive than copper.
Copper(II)
In general, a more reactive metal will displace a less sulphate
reactive metal from their salts in solution. solution
Chapter 19
Metals and Their Reactivity
Displacement Reactions
Zinc metal
If a piece of zinc is placed in
magnesium sulphate solution,
no reaction will take place.
This is because zinc is less
reactive than magnesium No reaction
(lower in the reactivity
series than magnesium) and
hence cannot displace
magnesium ions from its magnesium
sulphate
solution. solution
Chapter 19
Metals and Their Reactivity
Displacement of metal from their oxides
A more reactive metal can
displace a less reactive metal Potassium (K)
Most reactive
from its oxide when they are
heated together. Sodium (Na)
Calcium (Ca)
E.g. 2Al + Fe2O3 Al2O3 + 2Fe Magnesium (Mg)
Aluminium (Al)
This reaction is used in
the production of Zinc ( Zn)
“thermite”, which uses Iron (Fe)
the molten iron formed Lead (Pb)
to repair cracks on Copper (Cu)
railway lines. Silver (Ag) Least reactive
Chapter 19
Metals and Their Reactivity
Action of heat on metal carbonates
Carbonates decompose
when heated to produce Potassium (K) Carbonates not
decomposed by
the metal oxides and Sodium (Na) heat
carbon dioxide.
Calcium (Ca)
E.g. CaCO3 CaO + CO2 More difficult
Magnesium (Mg)
However, the more Aluminium (Al) Carbonates
reactive the metals Zinc ( Zn) decomposed
by heat
are, the more Iron (Fe)
difficult it is for their Lead (Pb)
carbonates to decompose. Copper (Cu)
Easier
Silver (Ag)
Chapter 19
Metals and Their Reactivity
Thermal stability of metallic compounds
Chapter 19
Metals and Their Reactivity
Reactions of metallic compounds
with acids and alkalis
Chapter 19
Metals and Their Reactivity
Quick Check 3
1. Arrange the following metals in order of their ease of forming positive
ions, starting from the most difficult:
lead, magnesium, sodium, iron, calcium, copper, potassium, zinc.
2. State what will happen when a piece of iron is placed in a beaker of
copper(II) sulphate solution. Write a chemical equation for the reaction.
3. Complete the following reactions.
(a) Mg(s) + ZnSO4(aq)
(b) Zn(s) + Pb(NO3)2(aq)
(c) Al(s)+ Zn(NO3)2(aq
(d) Cu(s) + ZnSO4(aq)
heat
(e) ZnCO3(s)
(f) Mg(s) + Al2O3(s) Solution
Chapter 19
Metals and Their Reactivity
Solution to Quick check 3
1. Copper, lead, iron, zinc, magnesium, calcium, sodium and potassium.
2. The iron will turn reddish-brown as it has displaced copper from the
copper(II) sulphate solution. The blue copper(II) sulphate will become
pale green in colour.
Fe(s) + CuSO4(aq) FeSO4(aq) + Cu(s)
3. (a) Mg(s) + ZnSO4(aq) MgSO4(aq) + Zn(s)
(b) Zn(s) + Pb(NO3)2(aq) Zn(NO3)2(aq) + Pb(s)
(c) 2Al(s)+ 3Zn(NO3)2(aq) 2Al(NO3)3(aq) + 3Zn(s)
(d) Cu(s) + ZnSO4(aq) No reaction
heat
(e) ZnCO3(s) ZnO(s) + CO2(g)
(f) 3Mg(s) + Al2O3(s) 3MgO(s) + 2Al(s)
Return
Chapter 19
Metals and Their Reactivity