• Non hydrocarbon • Functional group= carboxyl group,-COOH • -COOH, use to determine the Chemical reaction Naming the carboxylic acid
• Longest chain including carbon in
carboxyl group • Numbering longest chaincarbon in carboxyl group always be no 1. • Example CH3-CH2-CH-COOH | CH3 No of carbon, n Structure,Name n= 0 H-COOH , methanoic acid n=1 CH3COOH, ethanoic acid n=2 CH3CH2COOH, propanoic acid n=3 CH3CH2CH2COOH, butanoic acid n=4 CH3CH2CH2CH2COOH, pentanoic acid Persoalan
• Bagaimana asid etanoik CH3COOH
dihasilkan dalam makmal?
• Bagaimana dengan sifat fizik asid etanoik,
iaitu, warna, bau, takat didih, keadaan fizikal pada suhu bilik dan keterlarutan dalam air? Physical properties
• Low molecular mass Colourless liquid at
room temp Larger molecular mass (>10 C) wax-like solid • Has smell of vinegar/sharp • Solubility • <4 C--Very soluble in water • >5 C –solubility decrease Reaction of ethanoic acid with a metal Procedure : 1. About 2cm3 of dilute ethanoic acid is placed in a test tube. 2. A piece of clean magnesium ribbon is dropped into the test tube. 3. The test tube is closed to collect the gas liberated. the gas is tested with a lighted wooden splinter. 4. Steps 1 to 3 are repeated using zinc to replace magnesium. Metal Observation Magnesium •The Mg ribbon dissolves to form a colorless solution. •Effervescence occurs. •The colorless gas produced burns with a ‘pop’ sound. Zinc •The zinc powder dissolves to form a colorless solution. •Effervescence occurs. •The colorless gas produced burns with a ‘pop’ sound. Discussion 1. Magnesium reacts with dilute ethanoic acid to produce magnesium ethanoate and hydrogen gas. 2CH3COOH(aq) + Mg(s) Mg(CH3COO)2(aq) + H2(g)
2. Zinc reacts with dilute ethanoic acid to produced
zinc ethanoate and hydrogen gas. 2CH3COOH(aq) + Zn(s) Zn(CH3COO)2(aq) + H2(g) Reaction of ethanoic acid with a base Procedure : 1. About 2 cm3 of dilute ethanoic acid is placed in a test tube. 2. About 2 cm3 of 1.0 mol dm-3 sodium hydroxide is added to the acid and then the mixture is shaken. 3. The mixture is poured into an evaporating dish and heated to dryness. 4. The solid residue is examined. 5. Steps 1 to 4 repeated using one spatulaful of copper(II) oxide powder to replace 2 cm3 of sodium hydroxide solution. Base Observation
Sodium hydroxide •A colorless solution is
solution formed. •The residue formed is a white solid.
Copper (II) oxide •The black powder dissolves
to form a blue solution. •The residue formed is a blue solid. Discussion
1. Sodium hydroxide solution neutralises ethanoic
acid to form a salt, which is sodium ethanoate and water. CH3COOH + NaOH NaCH3COO + H2O
2. Ethanoic acid dissolves copper (II) oxide to
produce copper (II) ethanoate and water. 2CH3COOH + CuO Cu(CH3COO)2 + H2O Reaction of ethanoic acid with a metal carbonate Procedure: 1. About 2 cm3 of dilute ethanoic acid is palced in a test tube. 2. One spatulaful of calcium carbonate is added to the acid. 3. The test tube is closed with a stopper fitted with a delivery tube dipping into lime water. Any change to the lime water is noted. 4. Steps 1 to 3 are repeated using iron (III) carbonate to replace calcium carbonate. Metal carbonate Observation •The white powder dissolves to form a colorless solution. Calcium •Effervescence occurs carbonate •The colorless gas produced turns lime water milky. •The reddish-brown powder dissolves to form a brown Iron (III) solution. carbonate •Effervescence occurs •The colorless gas produced turns lime water milky. Discussion 1. Calcium carbonate reacts with dilute ethanoic acid to produced calcium ethanoate, water and carbon dioxide. 2CH3COOH + CaCO3 Ca(CH3COO)2 + H2O + CO2
2. Iron (III) carbonate reacts with dilute ethanoic
acid to produced iron (III) ethanoate, water and carbon dioxide 6CH3COOH + Fe2(CO3)3 2Fe(CH3COO)3 + 3H2O + 3CO2 Reaction of ethanoic acid with alcohol Procedure: 1. About 2 cm3 of glacial ethanoic acid is poured into boiling tube. 2. About 2 cm3 of absolute ethanol is added to the acid. The boiling tube is shaken to mix the liquid well. 3. A dropper is used to add about 1 cm3 of concentrated sulphuric acid to the mixture. The boiling tube is shaken well. 4. The mixture is carefully heated over a small flame . The mixture is allowed to boil gently for about 2 to 3 minutes. 5. A beaker is half-filled with some water. 6. The content of boiling tube are poured into the beaker. 7. Any change is observed. 8. Steps 1 to 7 is repeated using butan-1-ol to replace ethanol.