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PETROLEUM GEOSCIENCE
Curso:
Geología de los hidrocarburos
Alumno:
Espinoza Diaz Harold César 14160090
Profesor:
Edwin Mendiolaza Basaldúa
2017
CAPITULO 3. SEDIMENTARY GEOCHEMISTRY
HOW SEDIMENTS ARE PRODUCED
• The composition and physical properties of
sedimentary rocks are to a large extent
controlled by chemical processes during
weathering, transport and also during burial
(diagenesis).
• Weathering and abrasion of the grains
continues during transport and sediments
may be deposited and eroded several times
before they are finally stored in a
sedimentary basin.
• After deposition sediments. At low temperatures,
however, unstable minerals and also amorphous phases
may be preserved for a long time and there may be many
metastable phases. Reaction between water and
sediments. (200 – 250 Cº).
• Biological processes often accompany the purely
chemical processes, adding to the complexity. Bacteria
have been found to play an important role in both the
weathering and precipitation of minerals.
• In this chapter we shall examine the processes between
water and sediments from a simple physicalchemical
viewpoint.
• A number of concepts are particularly useful for describing and explaining
geochemical processes:
1. Ionic potential
2. Redox potential Eh
3. pH
4. Hydration of ions in water
5. Distribution coefficients
6. Isotopes
IONIC POTENTIAL
• Ionic potential (I.P.) may be defined as the ratio between the charge (valency) Z and the ionic radius
R: IP= Z / R
• The ionic potential is an expression of the charge on the surface of an ion, i.e. its capacity for
adsorbing ions.
• Ions with low ionic potential are unable to break the bonds in the water molecule and therefore
remain in solutionas hydrated cations(e.g.Na+,K+).
• The hydration strongly affects the chemical properties of the ion and its capacity to be adsorbed or
enter into the crystal structure of a mineral.
• The most soluble ions remain in the seawater until they are precipitated as salt when seawater is
concentrated during evaporation. In addition to the chlorides (i.e. NaCl, KCl), these are mainly salts
of cations with low ionic potential, and of anions with high ionic potential, e.g. CaSO4.2H2O,
Na2CO3 and carbonates such as CaCO3 (calcite), CaMg(CO3)2 (dolomite) and MgCO3(magnesite).
REDOX POTENTIALS (EH)
• Oxidation potential (E) is an expression of the tendency of an element to be oxidised, i.e. to give
up electrons so it is left with a more positive charge.
• This potential can be measured by recording the potential difference (positive or negative) which
arises when an element functions as one electrode in a galvanic element. The other electrode is a
standard one, normally hydrogen.
pH
• In nature the pH of surface water mostly lies between 4 and 9. Rainwater is frequently slightly
acid due to dissolved CO2, which gives an acid reaction: H2O+CO2 =H2CO3 (carbonicacid)
H2CO3 =H+ +HCO− 3 =2H+ +CO2− 3
• In areas with calcareous rocks or soils this sulphuric acid is immediately neutralised and the water
becomes basic. By contrast, in areas with acidic granitic rocks, the rock does not have sufficient buffer
capacity to counteract acid rain or acidic water produced by vegetation.
• The water near the surface of large lakes and the sea can have a high pH because CO2 is consumed
due to high organic production (photosynthesis).
• Seawater is a buffered solution, with a typical pH close to 8, though this varies somewhat with
temperature, pressure and the degree of biological activity.
• Eh and pH are important parameters for describing natural geochemical environments, and the diagram
obtained by combining these two parameters is particularly useful. The lower limit for Eh in natural
environments is defined by the line Eh=−0.059pH.
1. Oxidising and acidic
2. Oxidising and basic
3. Reducing and acidic
4. Reducing and basic
ISOTOPES
• The 87Rb−87Sr and the 40K−40Ar methods are the ones
most commonly used in determining the age of rocks. The
ratios between lead isotopes can also be employed
because of the 235U−207Pb, 238U−206Pb and
238Th−208Pb reactions.
• Isotope fractionation is a function of temperature,
however, and is much more effective with evaporation at
low temperatures than at high ones.
• In meteoric water there is a linear relation between the
deuterium/hydrogen ratio (D/H) and the δ18O.
CLAY MINERALS
• Mica (muscovite and biotite) lose some potassium which is replaced by
water (H2O, H3O+) to form illite (hydro mica).
Sheet silicates have a structure consisting of sheets of alternating layers
of SiO4 tetrahedra and octahedra. In the tetrahedral layers .
• Glauconite is a green mineral which forms on the seabed. It is a
potassium and iron bearing silicate somewhat similar to illite and
contains both di - and trivalent iron.
• Kaolinite consists just of a tetrahedral layer and an octahedral layer and
isvery stableat low temperatures. There are no positions in the structure
where exchange can precede easily,
• Chlorite is a mineral which consists of two tetrahedral layers and two
octahedral layers, totalling 14 Å.
WEATHERING
• Bioturbation plays an important role in changing the textural composition of the sediments after
deposition. The burrowing organisms eat mud and there by oxidise organic matter and physically
destroy the primary lamination. Sediments overturned by bioturbation become more exposed to
oxidation at the sea or lake bottom. Bioturbation maY reduce the porosity and permeability of
sandy laminae by mixing clay with clean sand.
• Carbonate cement in sandstones may form layers or concretions and in most cases is derived from
biogenic carbonate, particularly from organisms composed of aragonite. Siliceous organisms
composed of opal (e.g. diatoms or siliceous sponges) may be an important source of micro-quartz
coatings on quartz grains at greater depth.
METEORIC WATER FLOW AND MINERAL
DISSOLUTION
• Meteoric water is rainwater which infiltrates the
ground. Initially this water is distilled water and
therefore undersaturated with respect to all
minerals. The reactions between meteoric water
and the land surface are an important part of the
weathering process. Rainwater contains carbon
dioxide (CO2) and sulphur dioxide (SO2) from
the air and is therefore slightly acidic ,producing
carbonic acid(H2CO3)and sulphuric acid
(H2SO4).
• We see from these reactions that low K+/H+ ratios will drive the reactions to the right.
Dissolution of feldsparandmicaandprecipitationofkaoliniterequire that the reaction products,
Na+,K + and silica, are constantly removed and that there is a supply of new freshwater which
is undersaturated with respect to feldspar and mica. Without a through flow of water these
reactions stop because the reaction products on the right hand side of the equations are not
removed.
• The porewater does not have to be acidic for kaolinite to form, but the K+/H+ ratio must be
low. If the pH is high the K+ concentration has to be correspondingly lower.
MECHANICAL
COMPACTION OF
LOOSE SAND
SANDSTONERESERVOIRSBURIED
TOINTERMEDIATEDEPTH(2.0–3.5KM, 50–120◦C)
• In basins where there has been mostly continuous subsidence, reservoirs buried to
depths shallower than about 2.0–2.5 km are still loose or only poorly cemented, except
where there is carbonate cement or high geothermal gradients.
• Generally, in relatively well-sorted quartz arenites and feldspathic sandstones the
porosity is to a large extent destroyed by quartz cementation.
• Smectite may be present in some muddy, and particularly volcanic, sandstones which have
been flushed with limited amounts of meteoric water.
DEEPLY BURIED SANDSTONES (>3.5–4KM,>120◦C)
• Once quartz
cementation has started
and quartz overgrowth
has formed, quartz
cementation does not
stop until nearly all the
porosity is lost, unless
the temperature drops
below 70–80◦C.
FLUID INCLUSIONS IN QUARTZ CEMENT