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2
• The Periodic Table is a table of the chemical elements, ordered
by their atomic number (number of protons), electron
configurations, and recurring chemical properties.
• This ordering shows periodic trends, such as elements with
similar behaviour in the same column.
• In general, within one row (period) the elements are metals on
the left, and non-metals on the right.
• The semiconductors (ex: Si, Ge) fall in
Group IV (of the Mendeleev Periodic Table) or
Group 14 (of the Standard Periodic Table )
3
Periodic Table after Mendeleev (1869)
4
The Common or Standard Form Periodic Table
Group → 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
↓ Period
1 2
1
H He
3 4 5 6 7 8 9 10
2
Li Be B C N O F Ne
11 12 13 14 15 16 17 18
3
Na Mg Al Si P S Cl Ar
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
4
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
5
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
55 56 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
6 *
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
87 88 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
7 **
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Uut Fl Uup Lv Uus Uuo
57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
* Lanthanides
La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
This is an 18-column periodic table layout, which has come to be referred to as the common or standard form, on account of its
popularity. It is also sometimes referred to as the long form,
5
• Si Atom: 2-D representation.
• Nuc – Nucleus: Contains 14 Protons (+charge) and
14 Neutrons (no charge)
• and has 14 electrons (-ve charge) in orbits (shells)
around the Nuc
• There are 4 electrons in outer orbit or shell (valence
shell) called valence electrons.
Nuc
6
• We draw the structure of the Si atom as a 2D diagram
for convenience of visualization
• the orbiting electrons travel around the nucleus in 3-
dimensional orbits.
7
8
Allowed orbits
Nuc
+4
(a) (b)
10
• From the equation En= -13.6 (n Z/π)2 we get the energies in the
orbits as E1, E2,E3 etc.
• Then an energy level diagram can be plotted
Energy (eV)
E2 n=2
E1 n=1
11
• Rigidity of solids arises from the atoms held together by
inter-atomic forces called inter-atomic bonds.
• There are 3 types of bonds
1) Ionic - formed between 2 opposite charged ions
2) Covalent - formed by sharing electrons between 2 atoms
3) Metallic - formed between metal atoms
12
• Solid Si is formed by the 4 valence electrons sharing electrons
with 4 of its neighbours
Covalent Bond
+4 Each atom contribute 4 valence
electrons so the atom is called a
+4 +4 +4 tetravalent atom.
Shown the 2-D representation of
+4
the structure
Note: the valence shell is not full
13
n=4
Conduction Band (CB)
Eg
eV n=3 Valence Band (VB)
n=2
The outer two bands are named the Valence band and the Conduction band.
*Conduction properties of solids are governed by valence band electrons being
excited to the conduction band by the input of energy (thermal, electrical) into the
solid.
Eg is the energy gap between the valence and conduction bands and called the
forbidden energy gap because electrons can’t occupy the enery levels within Eg.
At absolute zero temperature (0K or -273C) : VB is “completely” full and CB is
completely empty
14
n=4 Conduction Band (CB)
Conduction Band (CB)
Eg Eg
eV n=3 Valence Band (VB) Valence Band (VB)
(c)
n=2
15
Intrinsic s-c
is a s-c in its extremely pure form.
• Si is the most widely used (and Ge to a lesser extent).
Generation of electrons (e-) and holes (h+)
e- and h+ are the mechanism by which s-c conduct electricity.
At absolute zero 0K (-273C) the s-c will have the ideal crystal
structure.
All valence e- are held tightly by their parent atoms and through
covalent bonds to other atoms.
Since e- are not free to move there is no conduction of electricity
and the s-c behaves as an insulator.
16
Crystal Classes
19
The energy band diagram for an Intrinsic s-c at room temperature is described by a
eV
CB a) Partially filled CB
Ef
b) Partially filled VB
Eg c) Narrow energy gap Eg ~ 1 eV
VB
At 0K no e- in CB – insulator.
At room temperature width of the gap is reduced and some e- jump into the CB
and s-c shows some conductivity.
The Fermi Level (Ef) is a thermodynamically determined energy indicator that
gives the probability of e- occupation in the energy band diagram.
Since e- and h+ are created as pairs, for a intrinsic s-c Ef lies in the middle of Eg.
20
Mechanism of h+ contribution to conductivity
Dislodged e- generates a h+.
An e- from a neighbouring covalent bond fills this hole leaving a h+ where it has
left.
This is the mechanism for h+ movement.
h+ move in opposite direction to e- and therefore h+ move in the direction of
conventional current flow. (Remember e- flow in the opposite direction to
conventional current flow).
+4
+4 +4
+4 +4
Fig 7.
21
Generation and Recombination of Carriers
e- Conduction Band
eV
Eg
h+ Valence Band
22
Generation and Recombination of Carriers:
• The e- and h+ generated are called free charge carriers and are
free to move within the crystal.
Conduction Band
eV
Eg
Valence Band 23
Generation and Recombination of Carriers:
Conduction Band
eV Photon Energy = Eg = hν
Eg Or thermal energy
Valence Band
24
• Intrinsic s-c has very small conductivity at room temperature
• so of no practical significance.
25
Extrinsic s-c
• The process of adding impurity atoms to the intrinsic s-c is called
doping.
• The impurities are so small they do not have any influence on the
crystal structure.
27
The Common or Standard Form Periodic Table
Group → 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
↓ Period
1 2
1
H He
3 4 5 6 7 8 9 10
2
Li Be B C N O F Ne
11 12 13 14 15 16 17 18
3
Na Mg Al Si P S Cl Ar
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
4
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
5
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
55 56 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
6 *
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
87 88 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
7 **
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Uut Fl Uup Lv Uus Uuo
57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
* Lanthanides
La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
This is an 18-column periodic table layout, which has come to be referred to as the common or standard form, on account of its
popularity. It is also sometimes referred to as the long form,
28
N- Type s-c:
• Examples of Group 15 impurities are P, Sb, As, Bi (have 5 valence e-).
• These elements donate excess e- carriers and are called donors or N-type
impurities.
• Out of the 5 valence e-, 4 form covalent bonds.
• The 5th e- is loosely bound.
• If detached this e- will be available for conduction.
• The energy required to detach this e- is about 0.05eV for Si
+4
+4
+4 +5 +4
Sb +4
5th electron
+4
Loosely bound
29
N- Type s-c:
• Addition of a pentavalent atom gives away or donates the 5th e-.
• After the donation the impurity atom becomes a +ve charged ion and is
known as a donor ion.
• This ion is bound by 4 covalent bonds and cannot move within the crystal
lattice.
• As a result, these ions do not contribute to the conduction of current.
• Thus for N-type s-c the current flow is due to e- and h+,
but a major part due to e-
.
Thus in N-type s-c
e- are known as majority carriers and
h+ as minority carriers.
30
• In a N- type s-c there are more e- in the CB than in the VB.
• The Fermi Level in a N-type s-c therefore lies closer to the CB
CB
Ef
eV
Eg
VB
31
P- Type s-c:
• Examples of Group 13 impurities are Ga, In, Al, B (have 3 valence e-).
• These elements make available +ve charge carriers because they create h+
which can accept e- and are called acceptor or P-type impurities.
• The 3 valence e- form 3 covalent bonds. The 4th is incomplete.
• The vacancy that exists in a covalent bond is a h+
• It acquires the 4th e- from a neighbouring atom to complete the covalent
bond.
• After doing this the In atom becomes a –ve charged immovable ion. The
energy involved in this capture is about 0.05eV for Si
+4
+4
+4 +3 +4
In +4
+4 hole 32
P- Type s-c:
• For P-type s-c the current flow is due to e- and h+, but a major part due to
h+.
Thus for P-type s-c
h+ are known as majority carriers and
e- as minority carriers.
CB
eV
Eg Ef
VB
33
Conduction in a Metal
J= σ E = q n µ E
where
σ is conductivity and E the applied electric field.
σ=qnµ
q = charge of an e-,
n = no of e- per unit vol (e- concentration),
µ = mobility of e-,
34
Intrinsic s-c:
Current density due only to movement of e- :
Jn= q n µn E;
µn= mobility of e-; n= e- concentration
36
Mass Action Law: Addition of N-type impurities decrease the number of h+
and addition of P-type impurities decrease the number of e- below a level
in intrinsic s-c.
Under thermal equilibrium n p = ni2 where ni is intrinsic concentration.
37
Diffusion Current in a s-c:
Consider a bar of P-type s-c having a non-uniform concentration of h+.
• Let the h+ in left side of YY’ be larger than the right side.
• Thus there exists a concentration gradient dp/dX whose value is given
by;
dp/dX= -(po-px)/X
where po and px are concentration of h+ to the left and on YY’
respectively, x is distance of YY’ from origin plane and
–ve sign indicates h+ concentration that decreases with increasing x.
h+
Y’ X
38
• Because of dp/dX the h+ from the left of YY’ will diffuse
towards the right side.
• This produces a current called the diffusion current.
h+
Y’ X
39
Similarly for N-type; Jn = -qDn dn/dX.
Then
40
PN Junction:
Note:
• the P and the N type s-c are not physically joined together.
• There is a continuous boundary between them.
• This is achieved with a single Si bar by doping the two
sides of the bar with Group 13 and Group 15 impurities.
41
Forming a PN junction – Start with intrinsic Si Group 14
e- h+
42
Add Group 13 and 15 impurities – ion implantation
13 15
- - - - - - + + + + + +
- - - - - - + + + + + +
- - - - - - + + + + + +
- - - - - - + + + + + +
P type N type
majority carriers h+ majority carriers e-
minority carriers e- minority carriers h+ 43
As soon as the junction is formed – Fermi levels line up
- - - - - - + + + + + +
- - - - - - + + + + + +
- - - - - - + + + + + +
- - - - - - + + + + + +
Eg CB
Ef
VB 44
As soon as the junction is formed
- - - - - - + + + + + +
- - - - - - + + + + + +
P N
- - - - - - + + + + + +
- - - - - - + + + + + +
h+ Diffuse e- Diffuse
45
As soon as the junction is formed
- - - - - - + + + + + +
- - - - - - + + + + + +
P N
- - - - - - + + + + + +
- - - - - - + + + + + +
46
As soon as the junction is formed
- - - - - - + + + + + +
- - - - - - + + + + + +
P N
- - - - - - + + + + + +
- - - - - - + + + + + +
Depletion Region
47
As soon as the junction is formed
- - - - - - + + + + + +
- - - - - - + + + + + +
P N
- - - - - - + + + + + +
- - - - - - + + + + + +
Depletion Region
48
As soon as the junction is formed
- - - - - - + + + + + +
- - - - - - + + + + + +
P N
- - - - - - + + + + + +
- - - - - - + + + + + +
VB = 0.7V
Distance
49
This is the unbiased PN junction.
50
Biasing the PN junction:
P N P N
+ - - +
V V
• They acquire energy from the voltage supply and enter the depletion region
and recreates the ionic structure.
• This reduces the width of the depletion region and the height VB of the
potential barrier.
FB P N
+ -
V
52
Forward Bias:
- - - - - - + + + + + +
P - - - - - - + + + + + + N
+ - - - - - - + + + + + + -
- - - - - - + + + + + +
V
For V < 0.7
VB
Distance
53
Forward Bias: For V ≥ 0.7
- - - - - - + + + + + +
P - - - - - - + + + + + + N
+ - - - - - - + + + + + + -
- - - - - - + + + + + +
Distance
54
Forward Bias:
• more majority carriers cross the junction and a large current will flow
through the junction.
• *Current in the external circuit is due to e- movement only, while in the s-c
will be due to e- and h+.
• Current in external circuit will flow as long as V is present.
• Current increases with increase in applied voltage over VB and is the
order of mA.
• V-I Characteristic
I
mA
Knee
VB V
Volts
55
Reverse Bias:
RB
P N
- +
V
56
Reverse Bias:
- - - - - - + + + + + +
P - - - - - - + + + + + + N
- - - - - - - + + + + + + +
- - - - - - + + + + + +
VB
Distance
57
Reverse Bias:
• No current flows due to majority carriers and the junction offers high
resistance.
• However, potential barrier helps minority carriers to sweep across junction.
• So there is a minority carrier current which is very small.
• This current is only dependent on temp and independent of applied voltage.
• It is called the Reverse Saturation current Is and is of the order of nA for
Si.
I
Is
V
Volt
s
Reverse
Bias
Region nA (Si)
58
Reverse Breakdown:
• The sudden increase occurs due to the breakdown in crystal structure and
when the applied voltage is removed the crystal structure will return to
normal unless permanently damaged.
59
Two processes cause junction breakdown,
1) Zener Breakdown
60
2) Avalanche Breakdown
61
V-I Characteristics of a PN junction (Diode)
Forward Bias
Region
Steep curve ≈ VB
VBR Is Kne
VB e V
Reverse Volt
Breakdown s
Region Reverse
Bias
Region nA (Si)
62
Diode Current Equation
• An equation that describe the forward and reverse characteristics of a
semiconductor diode.
Let I = Forward (or reverse) diode current,
Is = Reverse Saturation Current,
V = External voltage, +ve for Forward Bias, -ve for Reverse Bias
η = constant = 2 for low values of diode current (Si)
= 1 for for higher values
VT = Volt equivalent of temperature = T/11600
where T is absolute temperature in K.
At room temp (300 K), VT = 26mV.
The current equation for the forward biased diode can be approximated
by
I = Is {exp[V/(ηVT)] – 1}
• The current equation for the reverse biased diode can be obtained by
changing the sign of V,
I = Is {exp[-V/(ηVT)] – 1}
63
Circuit Symbol for a diode
A K
P N
A K
64
ΔVF
IF
V
VF
65
ΔVF
ΔIF
V
ΔVF
66
Junction Resistance
67
Power and Current Ratings
68
Temperature Effects
69
Diode Terminal Identification and Types of Diodes
A K A K A K
70
The Load Line
e= + R
i(t)
A sinωt ~
- v(t)
71
• To analyze the circuit we use the
Principle of Superposition.
• This principle says that a circuit containing two voltage
sources can be analyzed by determining the current in
the circuit due to each source acting alone and then
adding the results to find the current when both sources
are present.
e= + e=
R
A sinωt ~
i(t) R I A sinωt +~ R i
- v(t) -
V
= +
E E
72
+ e=
e= R
i(t) R A sinωt + R i
A sinωt ~ I
~
- v(t) -
V
= +
E E
I
E/R
E V 73
• Then we superimpose the diode forward bias curve on
the same graph
• The intersection point Q is called the quiescent point or
operating point of the diode.
• VF is the diode voltage and IF the diode current.
• For V > VB the voltage drop across the diode is
VB = 0.7 V for Si.
For analysis purposes the diode can be replaced with a
battery of 0.7V and with opposite polarity to E.
I
Diode FB R I
E/R
0.7V
Q E
IF
E V
VF
0.7V 74
• In the ac equivalent circuit we replace the diode with the
diode ac resistance rac which has a voltage drop VD
across it,
rac = rj + rB
Let rB = 0 for convenience then
rac ~ rj = 0.026 / IF
IF is given by the DC equivalent circuit as IF = (E – 0.7)/R
for V>VB
e=
A sinωt + R R IF
~ i(t)
0.7V
-
rac
E
75
e=
A sinωt + R i
~
-
rac
VD
76
e= + R
i(t)
A sinωt ~
- v(t)
77
• So we can draw the load line extremes in the V-I graph
and superimpose the diode forward bias curve
• As total voltage varies between vmin and vmax, the
intersection of all the load lines with the V–I
characteristic curve generate all the current voltage
combinations that are in the circuit.
• So we can visualize circuit operation as a point moving
continuously along the V-I diode curve between the
I
points A and B
(E+A)/R
E/R
(E-A)/R
A
Q
B
Vmin= E Vmax V
E-A =E+A
78
Example
79
Applications of Diodes – DC Power Supply
80
230V 50 Hz mains supply
81
Rectifier
• A rectifier is a device that allow current to flow through in
one direction only.
e(t) vR(t)
e(t)+~ i(t)
- vR(t)
R
t t
82
• During the +ve half cycle the diode is forward biased
and current will flow.
• During each –ve half cycle the diode is reverse biased
and no current flows (except for Is).
• Net effect is the conversion of an ac voltage into a
pulsating DC voltage, the fundamental step in the
construction of a DC power supply.
• The single diode is called a half wave rectifier.
83
84
Elementary DC Power Supplies
t t
e(t) + i(t)
~
- vL(t)
C RL
t t
Input Output
86
87
Zener Diode
• The Zener diode is a PN junction device and operates in the
reverse-breakdown region only
• The breakdown voltage Vz of a Zener diode is set by carefully
controlling the doping level during manufacture.
I
Vz
V
K IZK
Regulation
region
M IZM
Regulation
region
M IZM
89
• The circuit symbol and a practical equivalent circuit for a
Zener diode are
Circuit symbol A K
Practical equivalent
rz
Circuit Vz
Vz’
90
Zener diode Voltage Regulator
Rs
Is Iz IL
Vs RL
VL
Vz
91
Zener diode Voltage Regulator
Rs
Is Iz IL
Vs RL
VL
Vz
94
95
96