Professional Documents
Culture Documents
Homogeneous/Bubbly Heterogeneous/Churn-
Flow turbulent Flow
Global Parameters
A new hypothesis for hydrodynamic similarity proposed
140
Schematic of the CT Setup
120
100
z, cm
80
60
40
20
-8 -4 0 4 8
r, cm
1
He Tracer
Normalized CT Resp.
0.8
ADM Fitting
0.6
0.4
Overcoat
Collected fluorescence going to the
0.2 spectrometer
0
0 10 20 30 40 Probe Tip
t, s
C/C*
0.3 0.6
2
ADM Fitting
O2 0.4
CSTR Fitting
0.2
O2 0.2
0.1
0
O2
0 20 40 60 80
0 600 nm 600 nm t, s
0 0.05 0.1 0.15 0.2 0.25 0.3
ug, m/s Fluorescence quenching mechanism Comparison of Data Fitting Using CSTR and
This work Towell et al. (1972)-dc0.406m
Schematic of Setup Field et al. (1980)-dc3.2m Mangartz et al. (1981)-dc0.1m
ADM models
Joseph et al. (1984)-dc0.305m Kago et al. (1989)-dc0.12m
Wachi et al. (1990)-dc0.2m
Kantak et al. (1995)-dc0.25m
Shetty et al. (1992)-dc0.25m Air-water, 0.1MPa, ug=0.12m/s, z/L=0.8
Heat Transfer Coefficient Measurement
in Air-Water Bubble Column
Chengtian Wu, Muthanna Al-Dahhan
The instantaneous heat transfer coefficient(hi):
hi=Qi / (TSi—Tbi)
3
• The heat transfer probe measures the instantaneous local heat flux(Qi)
and the surface temperature(Tsi) of the probe.
• Three thermocouples are used to measure the bulk temperature(Tbi).
1
Air
0.92
5 6
0.88 1bar-3cm/s
8
1bar-30cm/s
1
7 10bar-3cm/s
0.84 10bar-30cm/s
0.8
0 0.2 0.4 0.6 0.8 1
r/R
1: filter; 2: rotameters; 3: high pressure bubble
column; 4: heat transfer probe; 5: thermocouple Radial profile of normalized heat transfer coefficient
probe; 6: amplifier; 7: DC power; 8: DAQ system. in the fully developed region of a bubble column
Catalyst To Oil Ratio Riser can identify the factor affecting the
Catalyst Inlet Temperature Feed
Vaporizing process & Reaction kinetics
Regenerated Catalyst
Steam
Present Contribution
Objectives
Estimating transport parameters like effective diffusivities and
adsorption/desorption isotherms by performing dynamic tracer study on
packed bed and autoclave reactor
Methodology
E
t
C
t
t
t
CHEMICAL REACTION ENGINEERING LABORATORY
Trickle Bed/
Measurement Techniques
Experimental Computation
Investigation Investigation
Collector system
• Measure liquid and gas 2D bed:
fluxes distribution at the
bottom of the column • Relate to capillary closure
• The overall objective is to assess the effectiveness of the reduced gamma ray
computed tomography for industrial process applications
TOTAL advisors: Pr. Philippe Tanguy, Jacques Bousquet and Nicolas Dromard.
CREL advisors: Pr. Milorad Dudukovic and Muthanna Al-Dahhan.
Operating conditions:
- real catalyst (porous cylindrical particles),
- 10 bar with pre-wetted beds,
- uniform gas-liquid distributor,
- air-water and air-oil systems.
17
CREL ANNUAL MEET 2005
Hydrodynamics in Trickle Bed Reactors: Experiments and CFD
Modeling
P. R. Gunjal, V.V. Ranade and R. V. Chaudhari
National Chemical Laboratory
Pune India
Wide Applications Key Characteristics
• Hydrodesulfurizations • Close to plug flow/ Low liquid hold-up
• • Suitable for slow reactions
Hydrocracking/hydrotreati • Poor heat transfer
ng • maldistribution and Difficult to scale-
• Hydrogenations up
• Waste water treatment
Trickle Bed Reactors
Key Issues
Experimental • Multi-scale Transport Computational Model
Processes
Measurements • Bed Characteristics • Multi-Fluid Model
• Wetting Efficiencies • Hetrogeneous Bed
• Pressure Drop • Flow Regimes
• Hydrodynamic Parameters
Definition
• Liquid Hold-up
• RTD • Inter-phase Closures
• Wall Pressure Fluctuations • Capillary Pressure Terms
CREL ANNUAL MEET 2005
Modeling of the Czochralski Crystal Growth
P. R. Gunjal, Milind Kulkarni and P. A. Ramachandran
Chemical Reaction Engineering Laboratory, Chemical Engineering Division
Washington University at St Louis, MO, 63112
MEMC Electronics Inc. St Peters, MO 63376
Natural wc
Convectio
n
Objectives Mel
t Operating Parameters
• Role of Fluid Dynamics
• Re=1-3x105 Ro=10
on Transport Cz Crystal Growth
Phenomenon Process • Pr=0.01 Ek=0.002
• Effect of Turbulence • Gr=5x1010 Ra=1-
• Interface Tracking 5x108
Packed bed/
Mixed tanks
Exothermic
Direct Reaction
Coupling Recuperative
Heat Coupling
Regenerative
Coupling
Endothermic
Reaction
Endothermic Exothermic
Endothermic
Exothermic
(1) CH 4 2O2 CO2 2 H 2O, H 773K 800kJ / Mol Short Contact Time
Reactors
(2) CH 4 H 2O CO 3H 2 , H 773K 222kJ / Mol (4-15 milli seconds)
Hohn & Schmidt, 2001
(3) CH 4 2 H 2O CO2 4 H 2 , H 773K 185kJ / Mol
(4) CO H 2O CO2 H 2 , H 773K 37 kJ / Mol
Partial Oxidation (Exo)
&
Steam Reforming (Endo) Steam Addition
Alkylation
Lighter Paraffins to Octane (LPG to gasoline), Linear Alkyl Benzene
•Currently hazardous liquid acid catalysts are used
•Substitution by solid acid catalysts is environmentally beneficial
Current Challenges
Catalyst deactivation Low selectivity
Catalyst leaching Low acid capacity
Catalyst instability High cost
Unacceptable activity Optimal reactor configurations
Modeling Approach
Catalyst Particle Reactor
Film Transport level Model
level Model
Methodology:
Compartmental Approach – Divides the reactor into number of inter-connected
well-mixed compartments
Incorporation of mean flow and turbulent parameters from complete CFD simulation
Results:
Mixing effect on reactor performance for multiple reactions
Effect of different feed locations captured
Processes and mini
and micro reactors
Goal Experimental
• Determine reaction operating S.S. reactor, L~30 m, D=0.762 mm
window (P, T, pO2, Ccat) for max.
conversion with high selectivity.
• Examine the effect of supercritical
CO2.
easurement techniques/ Bioreactors and Bioprocesses
Feeding Section Engineering
Reactor Laboratory
Analysis (BBE
Modeling
Cell N
Performance of the catalytic oxidation of Cell N
Objectives:
Design a technology to reduce nitrogen concentration from anaerobic sludge
digestion centrate at the New York City Department of Environmental Protection
(NYCDEP) wastewater facilities.
Accomplishments:
1. Reduce the effluent nitrogen levels to the allowable limit
2. Create a marketable product with revenues that compensate for the cost of
all chemical additives in the process
3. Reduce phosphorous levels in the effluent
4. Reduce struvite-scaling formation within piping
5. Dramatically reduce the amount of required aeration
Matthias Kroschel
Olaf Stange
defined residence
defined
times with narrow
flow properties
distribution
short response easy process control
time and automation
2005-10-06
Modular Microreaction System
Toolbox Applications Examples
Kinetic Characterization
Physical characterization
Vibrate bed
Measurement techniques/
Bioreactors and Bioprocesses
Engineering Laboratory (BBEL)
Objective studies:
Detectors
Three phase
system (GLS)
Gas
25 injection
150 mm
pipe (Dia
20
= 5 mm)
334 mm
153 mm
15
50m
Level 1 38mm m
10 140 mm 100
mm
220 mm
Levels at
which the CT
5 Level 1 mm scans have
been
conducted
0
0 1 2 3 4 5 6 7 8
26mm 40 mm 0
25 Angle Gas Hold up at Level 2
Flow pattern for sparger system with 5% (TS) Superficial gas velocity =7.35
solid loading slurry. Gad flow rate =3 lit/min cm/sec (flow rate = 5 lit/min)
Development of Multiple-Particle
Tracking Technique (MP-CARPT)
Mehul S. Vesvikar and Muthanna Al-Dahhan
• Advancing CARPT to next level to track
more than one particles simultaneously.
NaI (T1) crystal+
Photomultiplier
Same as previous Bicron 2M2/2-x
PC on a card
Under windows
Scaler Scaler
reactor to track two solids of different Also allows programming energy window, etc. Compact PCI
backplane
physical properties.
Flow and Shear Mapping in an
Impeller-Mixed Anaerobic Digester
using CARPT
Mehul S. Vesvikar and Muthanna Al-Dahhan
25
Objective:
To quantify the flow
20
15
10
distribution in an
anaerobic digester
5
mixed by mechanical
0
agitation using
0 1 2 3 4 5 6 7 8
Radial shear stress
CARPT
radial location (cm)
Flow pattern
Performance Study of a Pilot Scale
Anaerobic Digester
Mehul S. Vesvikar, Abhijeet Borole, Thomas Klasson,
Khursheed Karim and Muthanna Al-Dahhan
• Importance of scale of
operation in experiments for
obtaining reliable results.
Volumetric Expansion and Phase Transition of
Expanded Solvents Using an Optical Probe
Sean G. Mueller, Muthanna H. Al-Dahhan, Milorad P. Dudukovic
Conference Chairs:
Dr. Muthanna Al-Dahhan, Professor/Co-Director, Washington University
Dr. Kevin Hicks, Research Leader, USDA
Dr. Charles A. Abbas, Director, Archer Daniels Midland Company
Website: http://www.engconfintl.org/6aebody.html
Completed Thesis, 2004-2005
Solids Flow Mapping in Gas-Solid Risers
-Satish Bhusarapu
Modeling the Fluid Dynamics of Bubble Column Flows
-Peng Chen
Analyzing and Modeling of Airlift Photobioreactors for Microalgal and Cyanobacteria
Cultures
-Hu-Ping Luo
Catalytic Wet Oxidation Over Pillared Clay In Packed Bed Reactors: Experiments and
Modeling
-Jing Guo
Bubble Velocity, Size and Interfacial Area Measurements in Bubble Columns
-Junli Xue
Flow Distribution and Performance Studies of Gas-Liquid Monolith Reactor
-Shaibal Roy
The effect of shear on the performance and microbial ecology of anaerobic
digesters treating cow manure from dairy farms.
-Rubecca Hoffman