Raw materials can be classified into its sources raw materials come from natural deposits, agro plants, disposed materials and industrial / processed raw materials. Chemical composition : mole or weight percentage, weight or mole fraction bases refer to its chemicals compound or its oxides compound. Chemical compounds bases ( volumetric / gravimetric analysis, analytical instrument / GC, GC - MS etc.) can be expressed as a mole [?] fraction [?] component [?] I mi
Raw materials can be classified into its sources raw materials come from natural deposits, agro plants, disposed materials and industrial / processed raw materials. Chemical composition : mole or weight percentage, weight or mole fraction bases refer to its chemicals compound or its oxides compound. Chemical compounds bases ( volumetric / gravimetric analysis, analytical instrument / GC, GC - MS etc.) can be expressed as a mole [?] fraction [?] component [?] I mi
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Raw materials can be classified into its sources raw materials come from natural deposits, agro plants, disposed materials and industrial / processed raw materials. Chemical composition : mole or weight percentage, weight or mole fraction bases refer to its chemicals compound or its oxides compound. Chemical compounds bases ( volumetric / gravimetric analysis, analytical instrument / GC, GC - MS etc.) can be expressed as a mole [?] fraction [?] component [?] I mi
Copyright:
Attribution Non-Commercial (BY-NC)
Available Formats
Download as PPT, PDF, TXT or read online from Scribd
Enhancing quality / property of materials for getting its
higher added value
2. Beneficiation : every process carrying out , mechanically ,
physically for materials to meet the materials specification
required by industries / market
3. Beneficiation : any process which involve no chemical
reaction for getting higher added value
There are many types of raw materials used in industries : Classification of these raw materials can be divided into its sources raw materials come from natural deposits raw materials come from agro plants product raw materials come from disposed materials raw materials come from other industries activities Classification of raw materials based on its physical appearance as a solid materials as a liquid materials or may be gaseous materials ?? • both crude raw materials and industrial / processed raw material first should be identified according to its nature • Identification includes : • Chemical composition : mole or weight percentage , weight or mole fraction bases refer to its chemicals compound or its oxides compound chemical analysis ( volumetric / gravimetric ), analysis using analytical instrument ( AAS , GC , GC – MS etc.) • This identification means to determine or to distinguish what are the main chemicals compounds which should be in the crude or raw material purification processes ? • Physical properties of the crude or raw material : • grain size or particle size screen analysis ? • water content drying processes ? • chemical compounds bases ( volumetric / gravimetric analysis , analytical instrument / GC or GS - MS organic compounds bases) • oxides bases ( Atomic Absorption Spectrophotometer = AAS inorganic compounds bases ) • Can be expressed as a mole bases or weight bases Wi Xi = W1 + W2 + W3 + ....... + Wi
X i = weight ⋅ fraction ⋅ component ⋅ i
Wi = weight ⋅ of ⋅ component ⋅ i ⋅ in ⋅ crude / rawmaterial mi Yi = m1 + m2 + m3 + ....... + mi
Yi = mole ⋅ fraction ⋅ component ⋅ i
mi = mole ⋅ of ⋅ component ⋅ i ⋅ in ⋅ crude / rawmaterial
( X i ) MWi Yi = ( X 1 ) MW1 + ( X 2 ) MW2 + ( X 3 ) MW3 + ....... + ( X i ) MWi
X i = weight ⋅ fraction ⋅ component ⋅ i
MWi = molecularweight ⋅ of ⋅ component ⋅ i • identification of solid state crude / raw materials usually includes • oxide compounds , by using AAS ( Atomic Absorption Spectrophotometer dry or wet bases composition ) Al2O3 , SiO2 • mineralogy analysis , to determine the existing minerals which compose the crude / raw material by using XRD instrument analysis • for example : limestone CaCO3 chemical compound CaO oxide compound for CaCO3 Calcite mineral form of limestone Aragonite mineral form of limestone • Clay : AL2O3 2 SiO2H2O : aluminates silicate compound Al2O3 & SiO2 oxide compounds for clay kaolinite , montmorilonite, halloysite : minerals of clay • Identification of minerals using its basal spacing and its 2 θ value, it means that for specified crystalline form , it has the fixed basal spacing and specific 2θ value. • Basal spacing means the distances whish measured between crystal lattice surfaces , usually each mineral type has many basal spacing values , to identify the minerals needs at least 2 its corresponding basal spacing. • For example: clay minerals • kaolinite mineral has the basal spacing : 7.15 Ao , 3.566 Ao and 2.331 Ao • Montmorilonite mineral has the basal spacing :14.7 Ao 4.42 Ao, 1.49Ao • XRD can be used to identify the minerals qualitatively , just looking for the basal spacing or its 2 θ values which correspond to the minerals` basal spacing • Analysis quantitatively using XRD instrument needs the providing mineral standard. It can be done by comparing the reflected X-Ray beam counts between the mineral standard and sample for the same basal spacing or 2θ values • Comparing the counts of reflected X-Ray of one sample with others for the same basal spacing or 2θ value , can indicate the relatively mineral content. The higher the counts means having the higher mineral content • Keep in mind : XRD method analysis is suitable only for crystalline minerals , not for amorphous minerals • no particles in industries having single size • the size of these particle should be noted as ranges of its size • Usually particle sizes in term of Mesh size , mesh screen Tyler standard wire mesh • Mesh definition : • for smaller particles , Mesh is define as a number of holes each square inch of wire mesh
1 inch wire Mesh : 100
hole there are 100 holes each square inch 1 inch Screen aperture : the diameter / the opening of each hole in mesh screen • standard screen system , means that in each system consists of several mesh-screens, which its aperture is orderly specified • An = aperture of the nth screen from the top of the screen arrangement • An+1 = aperture of the (n+1)th screen from the top of the screen arrangement An = √2 An+1
Mesh number : 100 A100 = 0,147 mm
Mesh number : 150 A150 = 0,104 mm The diameter / size of particle which retained 150 Mesh and through 100 Mesh