Professional Documents
Culture Documents
Hazard Communication :
Labelling and SDS (1)
One of the objectives of the work
on the Globally Harmonized
System (GHS) is the development
of a harmonized communication
system, including Labelling, Safety
data sheets (SDS) and easily
understandable symbols, based on
classification criteria developed for
the GHS.
HAZARD COMMUNICATION -
LABELLING & SDS 2
GHS
Hazard Communication :
Labelling
HAZARD COMMUNICATION -
LABELLING & SDS 3
Hazard Communication
In the GHS Document
Chapter 1.4 - Hazard Communication : Labelling
• Target audiences
• Comprehensibility
• Comprehensibility testing methodology
• Translation
• Standardization
• Use of non-standardized or supplemental
information
• Updating information
• Confidential business information (CBI)
• Training
• Labelling procedures
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LABELLING & SDS 4
Labelling
The harmonized system for hazard communication includes
the appropriate labelling tools to convey information about
each of the hazard classes and categories in the GHS.
The use of symbols, signal words or hazard statements other
than those, which have been assigned to each of the GHS
hazard classes and categories, would be contrary to
harmonization.
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Labelling : Target audiences
Labels communicate the
hazard(s) according GHS
classification to target audiences
- Workplace
- Consumers
- Emergency responders
- Transport
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Labelling : Target audiences (1)
- Workplace
Employers and workers need to
know the hazards specific to the
chemicals used and or handled in
the workplace, as well as information
about the specific protective
measures required to avoid the
adverse effects that might be caused
by those hazards.
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Labelling : Target audiences (2)
- Consumers
The label in most cases is likely to be
the sole source of information readily
available to the consumer.
The label, therefore, will need to be
sufficiently detailed and relevant to
the use of the product.
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Labelling : Target audiences (3)
- Emergency responders
Emergency responders need information
on a range of levels.
To facilitate immediate responses, they
need accurate, detailed and sufficiently
clear information. This applies in the
event of an accident during transportation,
in storage facilities or at workplaces.
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Labelling : Target audiences (4)
- Transport
The UN Recommendations on the
Transport of Dangerous Goods, Model
regulations, cater for a wide range of
target audiences although transport
workers and emergency responders are
the principal ones. Others include
employers, those who offer or accept
dangerous goods for transport or load or
unload packages of dangerous goods
into or from transport vehicles, or freight
containers. HAZARD COMMUNICATION -
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Target audiences needs have been identified
Workplace - Employers and workers need to know the hazards specific to
the chemicals used and or handled in the workplace, as well as information
about the specific protective measures required to avoid the adverse effects
that might be caused by those hazards.
HAZARD COMMUNICATION -
LABELLING & SDS 14
GHS Pictograms
Signal Words:
“Danger” or “Warning”
are used to emphasis hazard and
indicate the relative of severity of
the hazard.
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LABELLING & SDS 17
Labelling
Hazard Statements:
Standard phrased assigned to a hazard
class and category to specified the nature
of the hazard.
Example : Acute Toxicity Oral ;
– category 1
“ Fatal if swallowed “
– Category 2
“Fatal if swallowed ”
– Category 3
“Toxic if swallowed”
– Category 4
“Harmful if swallowed”
– Category 5
“Maybe harmfulHAZARD COMMUNICATION -
if swallowed”
LABELLING & SDS 18
Label elements : Example 1 ( Acute
toxicity, oral)
(GHS Recommendation Annex 1 )
No
Pictograms
Symbol
Signal word
Danger Danger Danger Warning Warning
HAZARD COMMUNICATION - 19
LABELLING & SDS
Label elements : Example 2
( Carcinogenicity)
(GHS Recommendation Annex 1 )
Category 1A Category 1B Category 2
No symbol No symbol
HAZARD COMMUNICATION - 21
LABELLING & SDS
Labelling
Precautionary Statements
Precautionary Statements
Prevention Response Storage Disposal Reference
* Keep out of IF SWALLOWED: * Store locked up. Dispose of this ** Read directions/label/
reach of Immediately call a material and its Safety Data Sheet
children. POISON CONTROL container to ... . before use.
CENTER/doctor ... in accordance with
* Do not eat, local/ Specific treatment is
/physician.
drink or smoke regional/national/ urgent (see ... on this
when using this Show international label)
product. container/label regulation). ... reference to
/Safety Data Sheet Supplemental First Aid
* Wash hands when possible. Instruction.
thoroughly if immediate administration
after Induce vomiting (if of antidote is required.
handling. conscious).
- if knowledge of the
Avoid all chemical indicates
contact. this
action is not
contraindicated.
Give water/nothing * if likely to be used
to ** if likely to be used
drink. by the general commercially.
public.
Give a slurry of HAZARD COMMUNICATION - 24
activated charcoal
LABELLING & SDS
- if ingestion of a
Labelling
Product Identifier
Supplier Identification:
The name, address and telephone should
be provided on the label.
Supplemental Information:
non-harmonized information.
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Label example
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Precedence for the allocation of
symbols (1)
HAZARD COMMUNICATION -
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Precedence for the allocation of
symbols
> Skin/Eye
irritation
> Skin
sensitization,
Skin/Eye irritation
DANGER > WARNING
HAZARD COMMUNICATION -
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GHS Label Global Hazexy
Globalethylene
(2-Hazanol ) Product identifier
CAS No. 222-22-2
Pictograms
Hazard statements
・ Combustible liquid Hazard statements
・ Harmful if swallowed
・ Toxic in contact with skin
・ Cause serious skin burns and eye irritation
・ Cause serious eye irritation
Supplier:
United Nations Corp. Ltd. Supplier identification
1-1, Peace Ave. Geneva, Switzerland
TEL: 41 22 917 00 000 FAX: 41 22 917 00 000
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LABELLING & SDS
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GHS
Hazard Communication :
Continue !
HAZARD COMMUNICATION -
LABELLING & SDS 35
Globally Harmonized System of
Classification System of Classification and
Labelling of Chemicals (GHS)
Hazard Communication :
Labelling and SDS (2)
HAZARD COMMUNICATION -
LABELLING & SDS 37
Hazard Communication in the
GHS Document
Chapter 1.5, Hazard communication :
Safety data sheets (SDS)
Role of the SDS in the GHS
SDS format
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SDS Target Audiences
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Criteria for determining
whether a SDS should be
produced
SDS should be produced for all substances
and mixtures which meet the harmonized
criteria for physical, health or environmental
hazards under the GHS and for all mixtures
which contain substances that meet the
criteria for carcinogenic, toxic to reproduction
or specific target organ systemic toxicity in
concentrations exceeding the cut-off limits for
SDS specified by the criteria for mixtures.
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When is a SDS required?
SDS should be produced for all
substances and mixtures which
meet the harmonized criteria
under the GHS and for all
mixtures which contain
substances that meet the GHS
criteria exceeding the cut-off
limits for each
hazard class.
General guidance for compiling a
SDS
1.5.3.1 Cut-off values / concentration limits
SDS should be provided based on the generic
cut-off values / concentration limits indicated
in Table 1.5.1 :
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Cut-off values/Concentration limits for each health and
environmental hazard class
Cut-off value /
Hazard Class Concentration Limit
Acute Toxicity ≧ 1.0%
Skin Corrosion / Irritation ≧ 1.0%
Serious damage to eyes / eye irritation ≧ 1.0%
Respiratory / Skin Sensitization ≧ 1.0%
Mutagenicity: Category 1 ≧0.1%
Mutagenicity: Category 2 ≧ 1.0%
Carcinogenicity ≧ 0.1%
Reproductive Toxicity ≧ 0.1%
Specific Target Organ Systemic Toxicity ≧ 1.0%
(Single Exposure / Repeat Exposure)
HAZARD COMMUNICATION ≧
-
Hazardous to the Aquatic Environment
LABELLING & SDS
1.0% 45
Safety Data Sheets
Primarily workplace use
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SDS format (1)
The information in the SDS should be presented using the
following 16 headings in the order given below :
1. Identification
2. Hazard(s) identification
3. Composition / information on igredients
4. First-aid measures
5. Fire-fighting measures
6. Accidental release measures
7. Handling and storage
8. Exposure controls / personal protection
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SDS format (2)
9. Physical and chemical properties
10. Stability and reactivity
11. Toxicological information
12. Ecological information
13. Disposal considerations
14. Transport information
15. Regulatory information
16. Other information
A SDS is not a fixed length document. The length of the SDS should
be commensurate with the hazard of the material and the
information available.
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Minimum information for a SDS content
(1)
Identification of the ・ GHS product identifier.
1
・ Other means of identification.
substance or mixture
・ Recommended use of the chemical
and of the supplier and restrictions on use.
・ Supplier’s details (including name,
address, phone number etc).
・ Emergency phone number.
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Minimum information for a SDS content
(2)
Composition/ Substance
3
・ Chemical identity.
information on
・ Common name, synonyms, etc.
ingredients
・ CAS number, EC number, etc.
・ Impurities and stabilizing additives
NOTE : which are themselves classified
For information on and which contribute to the
ingredients, the competent classification of the substance.
authority rules for CBI take
priority over the rules for Mixture
product identification. ・ The chemical identity and
concentration or concentration
ranges of all ingredients which
are hazardous within the
meaning of the GHS and are
present above their cut-off
levels.
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Minimum information for a SDS content
(3)
4 First aid measures ・ Description of necessary measures,
subdivided according to the
different routes of exposure, i.e.
inhalation, skin and eye contact
and ingestion.
・ Most important symptoms/effects,
acute and delayed.
・ Indication of immediate medical
attention and special treatment
needed, if necessary.
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Minimum information for a SDS content
(4)
6 Accidental release ・ Personal precautions, protective
measures equipment and emergency
procedures.
・ Environmental precautions.
・ Methods and materials for
containment and cleaning up
7 Handling and ・ Precautions for safe handling.
storage ・ Conditions for safe storage,
including any incompatibilities.
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Minimum information for a SDS content (6)
10 Stability and ・ Chemical stability.
reactivity ・ Possibility of hazardous reactions.
・ Conditions to avoid (e.g. static
discharge, shock or vibration).
・ Incompatible materials.
・ Hazardous decomposition
products.
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Minimum information for a SDS content
(8)
14 Transport ・ UN number.
information ・ UN Proper shipping name.
・ Transport Hazard class(es).
・ Packing group, if applicable.
・ Marine pollutant (Yes/No).
・ Special precautions which a user
needs to be aware of or needs to
comply with in connection with
transport or conveyance either
within or outside their premises.
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Units
Numbers and quantities should be
expressed in units appropriate to the region
into which the product is being supplied. In
general, the International System of Units
(SI) should be used.
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Internationally-recognised
standards for SDS
ILO Recommendation 177 ( 1990 )
EU SDS Directive 91/155/EEC ( 1991 )
USA Standard ANSI Z 400.1 ( 1993 )
ISO SDS Standard 11014-1 ( 1994 )
Guidance on the preparation of SDS is
available as Annex 4 to “GHS Purple
book”
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GHS SDS (SAFETY DATA SHEET)
FORMAT
1. Identity of manufacturers/ suppliers
2. Hazard (s) identification
3. Composition/information on ingredients
4. First aid measures
5. Fire fighting measures
6. Accidental release measures
7. Handling and storage
8. Exposure control/personal protection
9. Physical and chemical properties
10. Stability and reactivity
11. Toxicological information
12. Ecological information
13. Disposal consideration
14. Transport information
15. Regulatory information
16. Other information
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GHS
Hazard Communication
Thank you
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