PH of a solution is calculated using the expression: pH = - log [H3O+]. Hydronium Ion Concentration can be found from pH by the reverse of the mathematical operation employed to find the pH. [OH-] = 10-pOH.
PH of a solution is calculated using the expression: pH = - log [H3O+]. Hydronium Ion Concentration can be found from pH by the reverse of the mathematical operation employed to find the pH. [OH-] = 10-pOH.
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PH of a solution is calculated using the expression: pH = - log [H3O+]. Hydronium Ion Concentration can be found from pH by the reverse of the mathematical operation employed to find the pH. [OH-] = 10-pOH.
Copyright:
Attribution Non-Commercial (BY-NC)
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Download as PPTX, PDF, TXT or read online from Scribd
you need to know the concentration of the hydronium ion in moles per liter (molarity). The pH is then calculated using the expression: pH = - log [H3O+].
Find the pH of a 0.0025 M HCl solution. The HCl is a strong acid and is 100% ionized in water. The hydronium ion concentration is 0.0025 M. Thus: pH = - log (0.0025) = - ( - 2.60) = 2.60 |
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The hydronium ion concentration can be found from the pH
by the reverse of the mathematical operation employed to find the pH. [H3O+] = 10-pH or [H3O+] = antilog (- pH)
What is the hydronium ion concentration in a solution that has a pH of 8.34? 8.34 = - log [H3O+] - 8.34 = log [H3O+] [H3O+] = 10-8.34 = 4.57 x 10-9 M On a calculator, calculate 10-8.34, or "inverse" log ( - 8.34). |
To calculate the pOH of a solution you need to know the
concentration of the hydroxide ion in moles per liter (molarity). The pOH is then calculated using the expression: pOH = - log [OH-]
What is the pOH of a solution that has a hydroxide ion concentration of 4.82 x 10-5 M? pOH = - log [4.82 x 10-5] = - ( - 4.32) = 4.32 | |
The hydroxide ion concentration can be found from the pOH
by the reverse mathematical operation employed to find the pOH. [OH-] = 10-pOH or [OH-] = antilog ( - pOH)
What is the hydroxide ion concentration in a solution that has a pOH of 5.70? 5.70 = - log [OH-] -5.70 = log[OH-] [OH-] = 10-5.70 = 2.00 x 10-6 M On a calculator calculate 10-5.70, or "inverse" log (- 5.70).
The pH and pOH of a water solution at 25oC are related by
the following equation. pH + pOH = 14 If either the pH or the pOH of a solution is known, the other can be quickly calculated.
A solution has a pOH of 11.76. What is the pH of this solution? pH = 14 - pOH = 14 - 11.76 = 2.24 Why pH + pOH = 14 Water ungergoes auto- or self-ionization as shown in the following equation. 2 H2O --> H3O+ + OH- An equilibrium is established between the ions produced and the unionized water. An equilibrium expression can be written for this system. Kw = [H3O+][OH-] Kw is used to represent the equilibrium constant for the ionization of water. It is a special notation of the general representation Kc. The value of Kw when measured at 25°C has been determined to be 1 x 10-14. Mathematically, if one takes the log of both sides of the equation, remembering that when numbers are multiplied their logs are added, we arrive at the following equation. log (1 x 10-14) = log [H3O+] + log [OH-] The log (1 x 10-14) = - 14. Thus, - 14 = log[H3O+] + log [OH-] Multiplying both sides of the equation by -1, we get 14 = - log [H3O+] - log [OH-] The - log [H3O+] is defined as the pH, and the - log [OH-] is defined as the pOH. Substituting into the equation yields the relationship between pH and pOH of a solution. | The pKa is calculated using the expression: pKa = - log (Ka) where "Ka" is the equilibrium constant for the ionization of the acid.
What is the pKa of acetic acid, if Ka for acetic acid is 1.78 x 10-5? pKa = - log (1.78 x 10-5) = - ( - 4.75) = 4.75 |
The Ka for an acid is calculated from the pKa by performing the reverse of the mathematical operation used to find pKa. Ka = 10-pKa or Ka = antilog ( - pKa)
Calculate the value of the ionization constant for the ammonium ion, Ka, if the pKa is 9.74. 9.74 = - log (Ka) -9.74 = log (Ka) Ka = 10-9.74 = 1.82 x 10-10 On a calculator calculate 10-9.74, or "inverse" log ( - 9.74). | The pKb is calculated using the expression: pKb = - log (Kb) where Kb is the equilibrium constant for the ionization of a base.
What is the pKb for methyl amine, if the value of Kb for methyl amine is 4.4 x 10-4? pKb = - log (4.4 x 10-4) = - ( - 3.36) = 3.36 |
The Kb for an acid is calculated from the pKb by performing the reverse of the mathematical operation used to find pKb. Kb = 10-pKb or Kb = antilog ( - pKb)
Calculate the value of the ionization constant, Kb, for aniline if the pKb is 9.38. 9.38 = - log (Kb) -9.38 = log (Kb) Kb = 10-9.38 = 4.17 x 10-10 On a calculator calculate 10-9.38, or "inverse" log ( - 9.38).