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Covalent bond Polarization of chemical bond Coordinate covalent bond Exception of octet rule Metallic bond
Periodic tabel Elements electronegativity Molecule polarity- net dipole moment Molecular shape
CHEMICAL BOND
- Chemical bond is an attractive force between atoms In the molecule. In the forming a chemical bond causes changing of electronic configuration. The changing of electronic configuration occur at the outermost shell (the valence shell), while at the inner shells dont undergo change
- The base of formation of a chemical bond is existence of a tendency of atoms to obtain stable electronic configuration such as the noble gas electronic configuration. - Basically, the chemichal bond is differentiated to 2 kinds, that is ionic bond and covalent bond Ionic bond and Covalent bond
Valence electron 2 8 8 8 8 8
- An electronic configuration, which is the outermost shell filled 8 electrons called octet configuration. - An electronic configuration, which is the outermost shell filled 2 electrons called duplet configuration. The noble gases, which have octet and duplet configuration, are very difficult to react with other elements.
Duplet rule is a tendency of electronic configuration change of an element atom to obtain the duplet configuration like Helium nobel gas.
The octet or duplet stable electronic configuration like noble gases can be obtained by : 1. lossing (release) or gaining electrons 2. pairing electrons.
1. Attainment of the stable electronic configuration of nobel gases by losing and gaining of electron
- The metal atoms to obtain of octet or duplet configuration by losing electron. Example: The atom of Na (Z = 11) loses one their valence electron to form the ion of Na+. The Na+ ion has the stable elelctronic configuration like the nobel gas of Ne (2 8) Sodium ion + e sodium atom Na : 2 8 1 Na+ : 2 8 + e - The nonmetal atoms to attain of octet or duplet configuration by gaining electron. Example: The atom of Cl (Z = 17) gains one electron to form the ion of ClThe Cl- ion has the stable electronic configuration like the nobel gas of Ar (2 8 8) Chlorine atom + e ion klor + e Cl : 2 8 7 Cl : 2 8 8 Attainment the stable electronic configuration like the nobel gases by losing and gaining of electron is the base of the forming of the ionic bond.
2. Attainment of the stable electronic configuration like the nobel gases by pairing of electron.
- The nonmetal elements to obtain octet or duplet configuration can be
done by donate its valence electron each other to form the shared pairs of electron
Example:
The atom of H (Z =1) can get the stable electronic configuration by donating of its electron each other, so that form one shared pair of electron (one bond pair of electron) in the H2 molecule.
In the H2 molecule each of the H atom has the stable electronic configuration like the noble gas of He. Attainment of the stable electronic configuration like the noble gas by the pairing of electrons is the base of the forming of the covalent bond.
Lewis symbol
A Lewis symbol is an atom symbol, which accompanied by its valence electrons. Its valence electrons can be representated by dot sign (.) or cros sign (x). The Lewis symbol is very useful in the chemical bond, mainly to illustrating of the covalent bond Example: excercise1 Hydrogen
Lewis Symbol of Period Elements of 1, 2, and 3 Group Period IA IIA IIIA IVA VA VIA VIIA VIIIA
Period 1 Period 2
Period 3
Ionic Bond
Ionic bond is a bonding between the positive ions and the negative ions that are caused by the electrostatic attractive force. The ionic bond especially formed between the atoms of metallic elements of group IA (alkali metals), group IIA (alkali earth metals and the atoms of nonmetallic elements of group VIIA (halogen), group VIA. Changing of electronic configuration that occurs in the formation of ionic bond as follow : - The metallic element losses its valence electron to form positive ion. Example: The metals of group IIA (alkaline earth metals) loss 2 valence electrons to form ion with charge of 2+.
Mg : 2 8 2 Mg2+ : 2 8 0 + 2e
- The nonmetallic element gains valence electron at its outer shell to form negative ion
Example: The nonmetals of group VIIA (halogen) gain 1 valence electron to form ion with charge of 1-
Cl : 2 8 7 +
Cl : 2 8 8
- By electrostatic force, one Li+ ion and one F ion combine to form ionic compound of LiF.
Example 2: CaCl2
By using Lewys symbol formation of CaCl2 ioninic bond can be explained as follow: - Ca atom (Z = 20) losses two its valence electrons to form ion of Ca2+ Ca2+ ion has stable electronic configuration like the noble gas of Ar (2 8 8)
- Cl atom gains one electron to form ion of ClCl- ion has stable electronic configuration like the noble gas of Ar ( 2 8 8)
Because CaCl2 is neutral, so one ion of Ca2+ bind two ions of ClOne Ca2+ ion and two Cl- ion by electrostatic attractive force join to form the ionic compound of CaCl2
Covalent Bond
Covalent bond is a bonding between non-metallic atoms that are caused by sharing pair of electron. In the formation of covalent bond, each non metallic atom donates one or more their valence electrons, it used to form the shared pair of electronn. The shared pair of electrons is often called as bond pair of electron. The pair of not shared electrons is called as lone pair of electron. By forming bond pair of electron, so each atom in that molecule has octet or duplet configuration like the noble gas. lone pair of electron.
In general, nonmetal of group IVA up to VIIA, the valence electron donated to form a covalent bond is as much as its insuffiency to reach the octet structure (8 of valence electrons).
Table 3.3. The valence electrons of nonmetal, Lewis symbol and the general number of electron which is donated in the formation of covalent bond Groups Valence Lewis symbols elektrons Donated electrons
VIIA (halogen)
VIA VA IVA
7
6 5 4
2
3 4
A compound, which has covalent bond is called covalent compound. A covalent compound, which is illustrated by using Lewis symbol called Lewis structural formula or electron-dot formula.
Example:
Covalent compound composed by the same nonmetal element is called molecular element. Example: H2, O2, O3, N2, F2, Cl2 Br2, I2, P4, S8. Covalent compound composed by the different nonmetal element is called molecular compound. Example: H2O, NH3, HCl, CO(NH2)2 , H2SO4, NaOH, C6H12O6.
: 1 17Cl : 2 8 7
- H atom donates one electron - Cl atom donates (8 7) = 1 its electron valence - It form one bond pair of electron (one covalent bond ) - In the HCl molecule : H atom has duplet structrure (2e) at its valence shell Cl atom has octet structure (8e-) at its valence shell. - A bond pair of electron can be illustrated/drawn by one bond line.
H Cl
2. CCl4
6C
: 2 4 17Cl : 2 8 7
- C atom donates four electron - Four atom of Cl, each of them donate 1 electron - It form four bond pair of electrons (4 covalent bond ) between C atom and four Cl atom. - In the CCl4 molecule, C atom and Cl atom has octet structure. - The fourth bond pair of electrons can be illustrated by four bond line.
Cl Cl C Cl
Cl
2. Triple bond
Example: N2 valence electron of N = 5 7N : 2 5 N atoms, each of them donate three electrons It form three bond pair of electrons (triple bond ). In the N2 molecule, the second of N atoms has octet structure.``
:2 2 One B atom and two Cl atoms form two bond pair of electrons. In BeCl2 molecule, the center atom of Be has four valence electrons (< 8 electrons), it cant fulfil octet rule.
b. BCl3 compound
5B
:2 3 One B atom and three Cl atoms form three bond pair of electrons In BCl3 molecule, the center atom of B has six valence electrons (< 8 electrons), it cant fulfil octet rule.
In PCl5 molecule, the center atom of P has electronic configuration of outermost shell more than eight electrons. A molecule that its center atom has electronic configuration of outermost shell more than 8 electrons is called a compound with extended octet structure. In PCl5 molecule, the center atom of P have a outermost shell electronic configuration of ten electron (> 8 electrons )
a. IF7 compound
Atomic number of I = 53 valence electron of I = 7 53I = 2 8 18 18 7 The seventh of valence electrons of I is used to form covalent bonds with F In IF7 molecule found the extended octet structure, at the center atom of I have a outermost shell configuration of fourteen electrons (> 8 electrons )
> H 2O Electronegativity O > H. The bond pair of electron stronger pulled to O atom than H atom. O atom more contain negative (-) and H atom more contain positive (+)
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H2
The second of H atom in H2 molecule has the equal electronegativity, therefore the bond pair of electron is pulled the equal strong by the second of H atoms. The bond of pair of electron exist exactly in the middle of the second of atoms, and the negative charge of bond pair of electron widespread equal to the second of H atoms. pada kedua atom H. The covalent bod dont undergoes polarization.
Polarity of Compound
Polarity of compound is a nature of the covalent compound that related with the polarization of covalent bond. Covalent compound can as polar or non polar compound. The polarity of compound can occur in binary (diatomic) or polyatomic compound
Polyatomic compound
Poly atomic compound is a compound that each molecule only consist of more of the different non-metal atoms. Polarity of polyatomic compound beside its bond kind polar covalent, also depent of the molecular shape, symmetry or unsymmetry
> Polyatomic compound, which is its central atom has not the lone pair of electron, its molecular shape is symmetry (symmetrical polyatomic compound)
> Polyatomic compound, which is its central atom has the lone pair of electron, its molecular shape is unsymmetry . (unsymmetrical polyatomic compound)
2. Polyatomic compound
Covalent compound formed by 2 or more atoms of different nonmetallic element , can polar or non polar, depend its molecular shape, symetric or unsymetric - Poliatomic compound that its central atom has not lone pair of electron, its molecular shape is symetric. - Poliatomic compound that its central atom has lone pair of electron, its molecular shape is unsymetric.
central atom lone electron pair bond electron pair surrounding atom
Metallic Bond
- Ikatan logam adalah suatu ikatan kimia yang disebabkan oleh interaksi antara atom-atom logam dengan elektron valensi yang mudah/bebas bergerak dari kulit luar atom satu ke kulit luar atom lainnya - Unsur logam mempunyai elektron valensi yang mudah bergerak/berpindah dari kulit luar atom satu ke kulit luar atom lainnya. - Elektron valensi yang bebas bergerak inilah yang menyebabkan logam mempunyai sifat penghantar panas dan penghantar listrik yang baik
EXERCISE
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THE END
Exercise 1
Draw the Lewis simbol of the atoms below: 5B, 7N, 8O, 9F, 13Al, 15P, 16S, 17Cl, 20Ca, 35Br
Exercise 2
Draw the Lewis formula of compunds below: a. I2 b. HCl c. CCl4 d. CH3Cl. e. N2
Exercise 3
Write the Lewis formula and structure formula of these compound : a. SCl4 b. CO2 c. PCl5 d. XeO3 e. OF2
Electron configuration
18Ar
Example : POCl3
e val = 5 + 6 + (3x7) = 32 Basic shape O Cl P Cl Cl
VSEPR
Dipole moment is a vector. The molecule's overall dipole moment is the result of the vector sum of all the bond dipoles within it
52
Periodic Tabel
Electronegativity
Dipole moment is a vector. The molecule's overall dipole moment is the result of the vector sum of all the bond dipoles within it