KHOA CNG NGH HA HC

TIU LUN MN PHN TCH CNG NGHIP

TI: PHN TCH HP KIM MANGAN

GVGD: Th.s Trn Nguyn An Sa SVTH: L Th Thu Hng MSSV: 09088791 MHP: 210408701

Ni dung
1. Tng quan v hp kim mangan

2.
3. 4. 5.

Phn tch mt s ch tiu trong feromangan

nh gi cc ch tiu Kt lun Ti liu tham kho

Tng quan v hp kim mangan

Hp kim mangan (Manganese Alloys) Hp kim mangan ng (Manganese Copper) Hp kim st mangan (ferro manganese) Hp kim mangan-ng-niken (manganin) Hp kim st mangan: cha lng ln mangan, c to thnh bng cch nung nng chy hn hp oxit MnO2, Fe2O3 vi carbon trong l cao. Hp kim st mangan c s dng nh l mt ioxit cho thp. Li th ca vic kt hp st oxit v mangan oxit vi nhau l nhit nng chy thp hn cc hp kim khi ch c s kt hp vi mangan oxit tinh khit .

Cc ch tiu trong hp kim feromangan

1. 2. 3. 4. 5. Phng php xc nh hm lng mangan Phng php xc nh hm lng silic Phng php xc nh hm lng photpho Phng php xc nh hm lng cacbon Phng php xc nh hm lng lu hunh

Phng php xc nh hm lng mangan

Phm vi p dng -nguyn tc

Phm vi p dng: xc nh tng hm lng mangan trong hp

kim feromangan Nguyn tc Ion mangan (II) c chun bng kalipemanganat trong mi trng trung tnh vi s c mt ca natri pirophotphat, xc nh im kt thc ca phn ng bng phng php chun in th Phng trnh 4Mn2+ +MnO42- +15H2P2O72- +8H+5[Mn(H2P2O7)3]3- +4H2O

Qui trnh

Tnh ton kt qu
Cng thc:
X (%) T V 100 m

Trong : T: l chun ca dung dch kali permanganat 0,05N (g/ml)

V: l th tch dung dch chun tiu hao (ml)

m: l khi lng mu trong phn dung dch xc nh (g)

Ch
Thit b: my chun in th

in cc ch th: tm bch kim hay dy bch kim

in cc so snh: in cc calomen bo ha

Mu khng tan ht trong axit nitric th ha tan phn cn cn li

vi 10ml hn hp HCl v HNO3 Ha cht: KMnO4 kt tinh li, pha dung dch chun KMnO4 0,05N v xc nh chun

Phng php xc nh hm lng silic

Phm vi p dng -Nguyn tc

Phm vi p dng : xc nh hm lng silic t 0,1% n 4%

trong feromangan bng phng php khi lng

Nguyn tc: ha tan mu trong hn hp acid nitric v acid sunfuricbc hi dung dch n thot khi trng tch kt ta acid silixic.Kt ta c lc, ra ri nung di dng dioxit silicx l ta SiO2 bng HF v tnh hm lng silic theo hiu s trc v sau khi x l kt ta SiO2 + 4HF SiF4 (KH) + 2H2O

Qui trnh

Tnh ton kt qu
Cng thc:
X

a b 0,4674 100
m

Trong : a: khi lng chn bch kim cng kt ta dioxit silic (g)

b: khi lng chn bch kim cng vi cn sau khi loi florua silic
(g) m: l khi lng mu(g) 0,4674 : h s chuyn dioxitsilic ra silic

Phng php xc nh hm lng photpho

Phng php xc nh photpho

C hai phng php xc nh photpho:

So mu phc axit d a mu xanh (khi hm lng photpho t

0,01 n 0,05%)

So mu phc axit d a photpho vanado-molipdic mu vng

(khi hm lng photpho ln hn 0,05% )

Phng php so mu phc axit d a mu xanh

Nguyn tc: Phng php da vo phn ng to thnh axit d a photpho molipdat mu vng v axit ny c kh v dng phc cht mu xanh trong mi trng axit HCl bng ion st (II) vi

hydroxilamin clorua
o mt quang bng quang ph k bc sng 840nm hay bng my so mu quang in (knh lc ) H3(P(Mo12O40)) + Mu vng ne- + nH+ H3(P(Mo12O40)Hn) mu xanh

Qui trnh

Phng php so mu phc axit d a mu vng

Nguyn tc Phng php da vo phn ng d a photpho vanado molipdic mu vng trong mi trng acid nitric o mt quang ca dung dch bng quang ph k vi bc sng bng 415nm hoc my so mu quang in knh lc mu xanh

PO43- + 12MoO42- + 27 H+

H3(P(Mo12O40)) +12H2O
mu vng

Qui trnh

Xy dng ng chun
1 V(ml) dd chun Photpho (B) V(ml) nc V(ml) dd HNO3 V(ml) hn hp thuc th Thi gian 0 2 2 3 6 4 10 5 14 6 18 7 22 8 25

30ml 8ml 10ml 20 phut sau khi phao quang

Tnh ton kt qu
Cng thc:

m 100 X m1

Trong : m l khi lng photpho tm c theo ng chun (g)

m 1 l khi lng mu trong phn dung dch xc nh (g)

X l hm lng photpho trong mu (%)

Ch
Pha dung dch amoni molipdat: 50g amonimolipdat+500ml nc

nng(50-60oC)khuy v cho vo 10ml HNO3lc qua giy lc

trung bnh Pha dun dch amonivanadat: 1,5g amonivanadat +250ml nc nng(50-60oC) nguipha long bng 250ml HNO3 Hn hp thuc th : trn dung dch amoni molipdat v dung dch

amonivanadat +80ml HNO3 bo qun trong chai nu

Ch
Pha dung dch tiu chun

Cn 0,4393g mui kali ihidro phosphat kt tinh li hai

ln v sy kh nhit 110oC ha tan bng nc ct nh mc 1 lit (dung dch A)

Pha long dung dch A gp 10 ln dung dch B( 1ml dung dch B cha 0,01mg photpho)

nh gi cc ch tiu
Nguyn tc Mangan Phng php chun in th Phng php khi lng 1. 2. 3. 1. 2. 3. Photpho Phng php trc quang 1. 2. Qui trnh gm cc giai on Phn hy mu Giai on tin chun Giai on chun Phn hy mu, gi li phn khng tan Xc nh khi lng SiO2+cn +chn nung Xc nh khi lng cn +chn nung Phn hy mu, loi yu t nh hng To phc d a mu xanh hoc vng o quang

Silic

Kt lun
Ferromangan l hp kim ph bin c s dng nhiu trong sn

xut gang thp, c tc dng lm tng cht lng sn phm, h gi

thnh sn xut. Do vic tip cn v phn tch cc ch tiu trong hp kim ny l iu cn thit. Khi xy dng qui trnh phn tch cc

ch tiu trong hp kim ferromangan ni ring v cc hp kim khc

ni chung th giai on x l mu l phc tp v kh thc hin hn so vi cc ch tiu ny trong mu nc v phn bn. Tuy nhin, vic li gip cho ngi hc c ci nhn tng quan khi xc nh cng mt ch tiu nhng trong cc mu khc nhau.

Ti liu tham kho

1. TCVN 3868-83 2. TCVN 3869-83 3. TCVN 3872-83 4. TCVN 3873-83 5. http://vi.wikipedia.org/wiki/Fer%C3%B4_mangan 6. http://en.wikipedia.org/wiki/Ferromanganese 7. http://www.google.com.vn/search?rlz=1T4ADFA_enVN427 VN451&q=fero%20mangan&gs_upl=0l0l1l358781lllllllllll0&u m=1&ie=UTF-8&hl=vi&tbm=isch&source=og&sa=N&tab=wi